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Are ionic liquids kosmotropic or chaotropic? An evaluation of available thermodynamic parameters for quantifying the ion kosmotropicity of ionic liquids
Abstract
Ion hydration is critically important to many biological applications, including protein unfolding. However, the hydration of ionic liquids (a new type of organic salts) is not well understood. One property for characterizing the effect of ion hydration is kosmotropicity. To quantify the ion kosmotropicity, this review evaluated several thermodynamic parameters including B‐coefficients, structural entropies, structural volumes, and ion mobility. The availability and reliability of experimental data and various models for these parameters were examined for ionic liquids. The relationship and comparison of these parameters are also discussed. Smaller pyridinium and imidazolium cations in ionic liquids are more likely to be chaotropes or borderline ions owing to their hydrophobic hydration. The kosmotropicity of anions varies. Copyright © 2006 Society of Chemical Industry
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Cites
Viscosity B-Coefficients of Ions in Solution
Jenkins, H. D. B., & Marcus, Y. (1995) · Chemical Reviews · doi:10.1021/cr00040a004 · Cited by 715
Cited by
Hofmeister effects: an explanation for the impact of ionic liquids on biocatalysis
Yang, Z. (2009) · Journal of Biotechnology · doi:10.1016/j.jbiotec.2009.04.011 · Cited by 398
Crystalline vs. Ionic Liquid Salt Forms of Active Pharmaceutical Ingredients: A Position Paper
Stoimenovski, J., MacFarlane, D. R., Bica, K., & Rogers, R. D. (2010) · Pharmaceutical Research · doi:10.1007/s11095-009-0030-0 · Cited by 358
Methods for stabilizing and activating enzymes in ionic liquids—a review
Zhao, H. (2010) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.2375 · Cited by 351
Self-citationWater structure and chaotropicity: their uses, abuses and biological implications
Ball, P., & Hallsworth, J. E. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp04564e · Cited by 261
Metadata
- Authors
- Zhao, H.
- Venue
- Journal of Chemical Technology & Biotechnology
- Publisher
- Wiley
- Published
- 2006-03-08
- Volume
- 81
- Issue
- 6
- Pages
- 877-891
- ISSN
- 0142-0356 (ISSN-L)
- 0268-2575
- 1097-4660
- OpenAlex
- W2073600573
- Cited by
- 182
- References
- 1
- FWCI
- 3.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhao, H. (2006). Are ionic liquids kosmotropic or chaotropic? An evaluation of available thermodynamic parameters for quantifying the ion kosmotropicity of ionic liquids. Journal of Chemical Technology & Biotechnology. https://doi.org/10.1002/jctb.1449
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