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Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4−. Alkanes and ethers
Abstract
Rate constants have been determined for the reactions of SO 4− with a series of alkanes and ethers. The SO 4− radical was produced by the laser‐flash photolysis of persulfate, S 2 O 82−. For methane, only an upper limit of 1 × 10 6 M−1 s−1 could be determined. For ethane, propane, and 2‐methylpropane, rate constants of 0.44, 4.0, and 10.5 × 10 7 M−1 s−1 were found. For ethyl and n‐propyl ether, rate constants of 1.3 × 10 8 and 2.2 × 10 8 M−1 s−1 were found and for 1,4‐dioxane and tetrahydrofuran, rate constants of 7.2 × 10 7 and 2.8 × 10 8 were obtained. The reaction of SO 4− with allyl alcohol was also studied and found to have a rate constant of 1.4 × 10 9 M−1 s−1.
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Citations
Cited by
Identification of Sulfate and Hydroxyl Radicals in Thermally Activated Persulfate
Liang, C., & Su, H.-W. (2009) · Industrial & Engineering Chemistry Research · doi:10.1021/ie9002848 · Cited by 1,301
Degradation of Chlorotriazine Pesticides by Sulfate Radicals and the Influence of Organic Matter
Lutze, H. V., Bircher, S., Rapp, I., Kerlin, N., Bakkour, R., Geisler, M., von Sonntag, C., & Schmidt, T. C. (2015) · Environmental Science & Technology · doi:10.1021/es503496u · Cited by 584
Electron transfer reaction rates and equilibria of the carbonate and sulfate radical anions
Huie, R. E., Clifton, C. L., & Neta, P. (1991) · International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry · doi:10.1016/1359-0197(91)90065-a · Cited by 311
Self-citationLee, Y.-C., Lo, S.-L., Chiueh, P.-T., & Chang, D.-G. (2009) · Water Research · doi:10.1016/j.watres.2009.03.052 · Cited by 257
Activation of persulfate with biochar for degradation of bisphenol A in soil
Liu, J., Jiang, S., Chen, D., Dai, G., Wei, D., & Shu, Y. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122637 · Cited by 189
Metadata
- Authors
- Huie, R. E., & Clifton, C. L.
- Venue
- International Journal of Chemical Kinetics
- Publisher
- Wiley
- Published
- 1989-08
- Volume
- 21
- Issue
- 8
- Pages
- 611-619
- ISSN
- 0538-8066 (ISSN-L)
- 1097-4601
- OpenAlex
- W2033463699
- Cited by
- 160
- References
- 0
- FWCI
- 4.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Huie, R. E., & Clifton, C. L. (1989). Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4−. Alkanes and ethers. International Journal of Chemical Kinetics. https://doi.org/10.1002/kin.550210802
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