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Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4−. Alcohols
Abstract
Rate constants have been determined for the reactions of SO 4− with a series of alcohols, including hydrated formaldehyde. The SO 4− radical was produced by the laser‐flash photolysis of persulfate, S 2 O 82−. Rate constants for the reactions of SO 4− with alcohols range from 1.0 × 10 7 for methanol to 3.4 × 10 8 M−1 s−1 for 1‐octanol. Rate constants for the reactions of SO 4− with deuterated methanol and ethanol are lower by about a factor of 2.5. For methanol, ethanol, and 2‐propanol, the temperature dependence of the rate constant was determined over the range 10–45°C.
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Cited by
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Wang, Z., Qiu, W., Pang, S.-Y., Guo, Q., Guan, C., & Jiang, J. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.1c04530 · Cited by 386
Liu, Y., He, X., Fu, Y., & Dionysiou, D. D. (2016) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2015.11.043 · Cited by 357
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Metadata
- Authors
- Clifton, C. L., & Huie, R. E.
- Venue
- International Journal of Chemical Kinetics
- Publisher
- Wiley
- Published
- 1989-08
- Volume
- 21
- Issue
- 8
- Pages
- 677-687
- ISSN
- 0538-8066 (ISSN-L)
- 1097-4601
- OpenAlex
- W1964675752
- Cited by
- 319
- References
- 0
- FWCI
- 5.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4−. Alcohols. https://app.cochat.ai/papers/10.1002/kin.550210807
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- Clifton, C. L., & Huie, R. E. (1989). Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4−. Alcohols. International Journal of Chemical Kinetics. https://doi.org/10.1002/kin.550210807
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