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Etude de la cristallisation des polymères. II. Structure lamellaire et repliement des chaînes du polyoxyéthylène
Abstract
Three polyethyleneoxide samples of molecular weights ranging from 6,000 to 28,000 have been studied with low‐angle X‐ray diffraction and dilatometry techniques. The thickness of the lamellae, the number of folds of the polymer chains, and the degree of crystallinity have been determined as functions of the crystallization temperature from the melt. A stepwise variation of these parameters has been established for the 6,000 and the 10,000 molecular weight samples. This phenomenon indicates that the chain ends are not located within the crystalline lamellae but are rejected in the thin amorphous layers separating the crystals.
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Citations
Cited by
Keller, A. (1968) · Reports on Progress in Physics · doi:10.1088/0034-4885/31/2/304 · Cited by 411
The Crystallization of Ultralong Normal Paraffins: The Onset of Chain Folding
Ungar, G., Stejny, J., Keller, A., Bidd, I., & Whiting, M. C. (1985) · Science · doi:10.1126/science.229.4711.386 · Cited by 329
In situ observation of low molecular weight poly(ethylene oxide) crystal melting, recrystallization
Chen, E.-Q., Jing, A. J., Weng, X., Huang, P., Lee, S.-W., Cheng, S. Z. D., Hsiao, B. S., & Yeh, F. (2003) · Polymer · doi:10.1016/s0032-3861(03)00557-3 · Cited by 43
(1980) · doi:10.1016/b978-0-08-092664-3.50007-9 · Cited by 16
Metadata
- Authors
- Arlie, P. J. P., Spegt, P., & Skoulios, A.
- Venue
- Die Makromolekulare Chemie
- Publisher
- Wiley
- Published
- 1967-05-26
- Volume
- 104
- Issue
- 1
- Pages
- 212-229
- ISSN
- 0025-116X (ISSN-L)
- OpenAlex
- W2150151546
- Cited by
- 168
- References
- 0
- FWCI
- 9.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Etude de la cristallisation des polymères. II. Structure lamellaire et repliement des chaînes du polyoxyéthylène. https://app.cochat.ai/papers/10.1002/macp.1967.021040122
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- Arlie, P. J. P., Spegt, P., & Skoulios, A. (1967). Etude de la cristallisation des polymères. II. Structure lamellaire et repliement des chaînes du polyoxyéthylène. Die Makromolekulare Chemie. https://doi.org/10.1002/macp.1967.021040122
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