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Etude de la cristallisation des polymères. II. Structure lamellaire et repliement des chaînes du polyoxyéthylène

Arlie, Par J. P., Spegt, P., Skoulios, A.·1967·Die Makromolekulare Chemie

Abstract

Three polyethyleneoxide samples of molecular weights ranging from 6,000 to 28,000 have been studied with low‐angle X‐ray diffraction and dilatometry techniques. The thickness of the lamellae, the number of folds of the polymer chains, and the degree of crystallinity have been determined as functions of the crystallization temperature from the melt. A stepwise variation of these parameters has been established for the 6,000 and the 10,000 molecular weight samples. This phenomenon indicates that the chain ends are not located within the crystalline lamellae but are rejected in the thin amorphous layers separating the crystals.

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Metadata

Authors
Arlie, P. J. P., Spegt, P., & Skoulios, A.
Venue
Die Makromolekulare Chemie
Publisher
Wiley
Published
1967-05-26
Volume
104
Issue
1
Pages
212-229
ISSN
0025-116X (ISSN-L)
OpenAlex
W2150151546
Cited by
168
References
0
FWCI
9.01
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Etude de la cristallisation des polymères. II. Structure lamellaire et repliement des chaînes du polyoxyéthylène. https://app.cochat.ai/papers/10.1002/macp.1967.021040122
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Arlie, P. J. P., Spegt, P., & Skoulios, A. (1967). Etude de la cristallisation des polymères. II. Structure lamellaire et repliement des chaînes du polyoxyéthylène. Die Makromolekulare Chemie. https://doi.org/10.1002/macp.1967.021040122

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.