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Physico‐Mechanical Properties of Biodegradable Starch Nanocomposites
Open accessAbstract
Nanocomposites of cassava starch reinforced with waxy starch nanocrystals were prepared. They showed a 380% increase of the rubbery storage modulus (at 50 °C) and a 40% decrease in the water vapor permeability. X‐ray spectra show that the composite was more amorphous than the neat matrix, which was attributed to higher equilibrium water content in the composites. TGA confirmed this result and its thermal derivative suggested the formation of hydrogen bonding between glycerol and the nanocrystals. The reinforcing effect of starch nanocrystals was attributed to strong filler/matrix interactions due to the hydrogen bonding. The decrease of the permeability suggests that the nanocrystals were well dispersed, with few filler/filler interactions. magnified image
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Cites
Plasticized starch/tunicin whiskers nanocomposites. 1. Structural analysis
Anglès, M. N., & Dufresne, A. (2000) · Macromolecules · doi:10.1021/ma0008701 · Cited by 667
Self-citationImprovement of starch film performances using cellulose microfibrils
Dufresne, A., & Vignon, M. R. (1998) · Macromolecules · doi:10.1021/ma971532b · Cited by 409
Self-citation
Cited by
Starch Nanoparticles: A Review
Le Corre, D., Bras, J., & Dufresne, A. (2010) · Biomacromolecules · doi:10.1021/bm901428y · Cited by 1,046
Self-citationPlant-derived nanostructures: types and applications
Mohammadinejad, R., Karimi, S., Iravani, S., & Varma, R. S. (2016) · Green Chemistry · doi:10.1039/c5gc01403d · Cited by 437
Preparation, characterization and utilization of starch nanoparticles
Kim, H.-Y., Park, S. S., & Lim, S.-T. (2015) · Colloids and Surfaces B: Biointerfaces · doi:10.1016/j.colsurfb.2014.11.011 · Cited by 419
Preparation and application of starch nanoparticles for nanocomposites: A review
Le Corre, D., & Angellier-Coussy, H. (2014) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2014.09.020 · Cited by 271
Desjardins, S. M., Laamanen, C. A., Basiliko, N., & Scott, J. A. (2020) · Environmental Reviews · doi:10.1139/er-2020-0004 · Cited by 20
Metadata
- Authors
- García, N. L., Ribba, L., Dufresne, A., Aranguren, M. I., & Goyanes, S.
- Venue
- Macromolecular Materials and Engineering
- Publisher
- Wiley
- Published
- 2009-03-09
- Volume
- 294
- Issue
- 3
- Pages
- 169-177
- ISSN
- 1438-7492 (ISSN-L)
- 1439-2054
- OpenAlex
- W2012117690
- Cited by
- 231
- References
- 2
- FWCI
- 4.92
- Type
- journal article
- Language
- en
- Open access
- green
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- García, N. L., Ribba, L., Dufresne, A., Aranguren, M. I., & Goyanes, S. (2009). Physico‐Mechanical Properties of Biodegradable Starch Nanocomposites. Macromolecular Materials and Engineering. https://doi.org/10.1002/mame.200800271
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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