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The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Emission and Emissive Mechanism of Nonaromatic Oxygen Clusters

Wang, Yunzhong, Bin, Xin, Chen, Xiaohong, Zheng, Shuyuan, Zhang, Yongming, Yuan, Wang Zhang·2018·Macromolecular Rapid Communications

Abstract

Nonaromatic luminophores without remarkable conjugates have aroused great attention. Their emission mechanism, however, remains an open question. Meanwhile, previous studies generally focus on aliphatic amine and/or carbonyl‐containing systems; those with merely oxygen moieties (i.e., ether, hydroxyl) are scarcely touched. Recently, the clustering‐triggered emission (CTE) mechanism is proposed to rationalize the emission of nonconventional luminophores, according to which compounds bearing purely oxygen moieties can also be emissive. To check this conjecture, herein, both nonaromatic compound of xylitol and polymers of PEG and F127 are studied, which are found to be emissive in concentrated solutions and solids. Furthermore, cryogenic‐persistent phosphorescence of the compounds and even persistent room temperature phosphorescence of xylitol crystals are observed. Additionally, their potential application as Fe 3+ sensors is demonstrated. These results not only verify the rationality of the CTE mechanism but also suggest the possibility to discover and design new luminophores according to it.

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Metadata

Authors
Wang, Y., Bin, X., Chen, X., Zheng, S., Zhang, Y., & Yuan, W. Z.
Venue
Macromolecular Rapid Communications
Publisher
Wiley
Published
2018-09-03
Volume
39
Issue
21
Pages
e1800528-e1800528
ISSN
  • 1022-1336 (ISSN-L)
  • 1521-3927
OpenAlex
W2889872342
Cited by
168
References
2
FWCI
6.05
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Emission and Emissive Mechanism of Nonaromatic Oxygen Clusters. https://app.cochat.ai/papers/10.1002/marc.201800528
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Wang, Y., Bin, X., Chen, X., Zheng, S., Zhang, Y., & Yuan, W. Z. (2018). Emission and Emissive Mechanism of Nonaromatic Oxygen Clusters. Macromolecular Rapid Communications. https://doi.org/10.1002/marc.201800528

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