Contribution of Supercritical CO2 to the Preparation of Aliphatic Polyesters and Materials Thereof
Abstract
This paper is a short review of the most recent achievments of CERM in the synthesis of poly (ϵ‐caprolactone) (PCL) and polylactides (PLA) in supercritical carbon dioxide (sc CO 2). In addition to the macromolecular engineering of these aliphatic polyesters, nanocomposites and PCL microspheres have been prepared with the assistance of this supercritical fluid.
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ROP of εCL in scCO2 has been carried out in the presence of various poly(tetrahydroperfuorodecylacrylate-b-capro-lactone) diblock copolymers.
“For instance, ROP of εCL in scCO 2 has been carried out in the presence of various poly(tetrahydroperfuorodecylacrylate-b-capro-lactone) diblock copolymers [93].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [93]
Micro-spheres have been prepared with [PCL(20 K)-b-PAC8(40 K)] surfactant under conditions: 10 vol.% CL, Mn,th=20 k; 5 wt.% surfactant, 40 °C, 300 bar, 400 rpm, 15 h.
“Micro-spheres have accordingly been prepared with [PCL(20 K)-b-PAC8(40 K)] surfactant, (conditions: 10 vol.%CL, Mn,th=20 k ; 5 wt.% surfactant, 40 °C, 300 bar, 400 rpm, 15 h) as illustrated in Fig. 3a.”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [93]
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Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆
JEROME, C., & LECOMTE, P. (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2008.02.008 · Cited by 590 · see citing works
Recent Developments in Ring-Opening Polymerization of Lactones
Lecomte, P., & Jérôme, C. (2011) · Advances in Polymer Science · doi:10.1007/12_2011_144 · Cited by 163 · see citing works
- Authors
- Stassin, F., & Jérôme, R.
- Affiliations
- University of Liège (BE)
- Corresponding author
- Jérôme, R.
- Venue
- Macromolecular Symposia
- Publisher
- Wiley
- Published
- 2004-10
- Volume
- 217
- Issue
- 1
- Pages
- 135-146
- ISSN
- 1022-1360 (ISSN-L)
- 1521-3900
- OpenAlex
- W2054248799
- Cited by
- 15
- References
- 0
- Citations by year
- 2023: 1 · 2019: 1 · 2017: 1 · 2016: 3 · 2013: 1 · 2012: 1
- FWCI
- 0.18
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Symposia (publishedVersion)
- Open Repository and Bibliography (University of Liège) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- supercritical carbon dioxide, aliphatic polyesters, polycaprolactone, polylactic acid, polymerization in supercritical fluids, macromolecular engineering, nanocomposites
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