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Cited by 409Organic Electronics and PhotovoltaicsConducting polymers and applicationsOrganic Light-Emitting Diodes Research

The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.

Review of electronic and optical properties of semiconducting π‐conjugated polymers: applications in optoelectronics

Moliton, André, Hiorns, Roger C·2004·Polymer International

Abstract

A general overview of the optoelectronic properties of π‐conjugated polymers is presented. Two types of polymer are discerned: interchangeable structures of the same energy (degenerate), such as polyacetylene; and non‐degenerate polymers, such as poly( para ‐phenylene). The band structures of degenerate and non‐degenerate polymers are related to their conductivities in doped and non‐doped states. In both cases, disorder and impurities play an important role in conductivity. Polarons, bipolarons and excitons are detailed with respect to doping and charge transfers. Given the fibrillic nature of these materials, the variable range hopping (VRH) law for semiconducting polymers is modified to account for metallic behaviours. Optoelectronic properties—electroluminescence and photovoltaic activity—are explained in terms of HOMO and LUMO bands, polaron‐exciton and charge movement over one or more molecules. The properties of H‐ or J‐type aggregates and their effects on transitions are related to target applications. Device structures of polymer light‐emitting diodes are explicitly linked to optimising polaron recombinations and overall quantum efficiencies. The particularly promising use of π‐conjugated polymers in photovoltaic devices is discussed. Copyright © 2004 Society of Chemical Industry

Overview

Integrity signals

Registry

Crossref · 10.1002/pi.1587

Cites

43 of 43 references verified0 citation errors · 0 not checkable

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Citations

Cites

Show all 43 references

Research works printed but not linked: 14

  1. Moliton A, 2003, Optoélectronique moléculaire et polymère: des concepts aux composants
  2. 10.1002/1521-3773(20010716)40:14<2591::AID-ANIE2591>3.0.CO;2-0 · DOI
  3. 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO;2-A · DOI
  4. Ashcroft NW, 1976, Solid State Physics
  5. Ioffe AF, 1960, Noncrystalline, Amorphous and Liquid Electronic Semiconductors
  6. Moliton A, 1998, Handbook of Conducting Polymers
  7. Brédas JL, 1981, Int J Quantum Chem, 15, 231
  8. ZuppiroliL BussacMN PaschenS ChauvetO ForroL BujardP KaiKandWernetW Hopping in Conducting Polymers Proceedings of the 5th International Conference on Hopping and Related Phenomena ed by Addkins CJ Long AR and McInnes JA World of Information Glasgow (1994).
  9. Brédas JL, 1982, Phys Rev B, 26, 371
  10. Leising G, 1998, Handbook of Conducting Polymers
  11. 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO;2-A · DOI
  12. 10.1063/1.359792 · DOI · Paper page
  13. OukachmihM Les cellules photovoltaïques à base de matériaux organiques dicotiques PhD thesis Université de Toulouse France (2003).
  14. Boulben A, 2004, Les cellules solaires organiques atteignent 5 % de rendement, L'Usine nouvelle, 2901, 37

Cited by

Items 101–200 of 406

Metadata

Authors
Moliton, A., & Hiorns, R. C.
Affiliations
Centre National de la Recherche Scientifique (FR)
Corresponding author
Moliton, André
Venue
Polymer International
Publisher
Wiley
Published
2004-07-19
Volume
53
Issue
10
Pages
1397-1412
ISSN
  • 0959-8103 (ISSN-L)
  • 1097-0126
OpenAlex
W1991832974
Cited by
409
References
43
Citations by year
2026: 25 · 2025: 32 · 2024: 13 · 2023: 18 · 2022: 20 · 2021: 26 · 2020: 29 · 2019: 19 · 2018: 9 · 2017: 16 · 2016: 23 · 2015: 20 · 2014: 15 · 2013: 16 · 2012: 19
FWCI
14.00
Type
journal article
Language
en
Open access
closed
Locations
  • Polymer International (publishedVersion)
  • HAL (submittedVersion)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
  • Physical Sciences › Materials Science › Polymers and Plastics › Conducting polymers and applications
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
Keywords
conjugated polymers, semiconducting polymers, optoelectronic properties, polyacetylene, poly(p-phenylene), electronic band structure, doping, conductivity, polarons, bipolarons, excitons, charge transfer, variable range hopping, metallic behavior, electroluminescence, H-aggregates, J-aggregates, polymer light-emitting diodes, polaron recombination, quantum efficiency, polymer solar cells

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