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Supramolecular polymer chemistry—scope and perspectives
Abstract
The connection of molecular monomers through non‐covalent intermolecular interactions leads to the formation of polymolecular entities defining a supramolecular polymer chemistry. The basic features of this field are presented and illustrated by some selected results. Thus, the molecular recognition directed association between monomers bearing complementary hydrogen bonding groups leads to linear supramolecular polymers and liquid crystals. Also, rigid rod, two‐dimensional, metal coordination‐based, side‐chain and cross‐linked supramolecular polymeric entities may be envisaged and several types have been generated. Like supramolecular materials in general, supramolecular polymers are reversible, constitutionally dynamic materials, capable of modifying their constitution by exchanging, recombining, incorporating components. They may present a variety of novel properties and behave as adaptive materials. © 2002 Society of Chemical Industry
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Cited by
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Demichelis, R., Raiteri, P., Gale, J. D., Quigley, D., & Gebauer, D. (2011) · Nature Communications · doi:10.1038/ncomms1604 · Cited by 583
Supramolecular Chemistry and Self-Assembly in Organic Materials Design
Stupp, S. I., & Palmer, L. C. (2014) · Chemistry of Materials · doi:10.1021/cm403028b · Cited by 513
Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers
Wang, F., Han, C., He, C., Zhou, Q., Zhang, J., Wang, C., Li, N., & Huang, F. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8035465 · Cited by 448
Triple-shape memory polymers based on self-complementary hydrogen bonding
Ware, T., Hearon, K., Lonnecker, A., Wooley, K. L., Maitland, D. J., & Voit, W. (2012) · Macromolecules · doi:10.1021/ma202098s · Cited by 192
Star-shaped and branched polylactides: Synthesis, characterization, and properties
Michalski, A., Brzezinski, M., Lapienis, G., & Biela, T. (2019) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.10.004 · Cited by 158
Metadata
- Authors
- Lehn, J.
- Venue
- Polymer International
- Publisher
- Wiley
- Published
- 2002-10
- Volume
- 51
- Issue
- 10
- Pages
- 825-839
- ISSN
- 0959-8103 (ISSN-L)
- 1097-0126
- OpenAlex
- W2067803690
- Cited by
- 520
- References
- 0
- FWCI
- 10.42
- Type
- journal article
- Language
- en
- Open access
- closed
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