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The DOI matches its Crossref record; 61 of the 61 references it cites were found in a registry or an index.

Forever young: polycyclic aromatic hydrocarbons as model cases for structural and optical studies

Rieger, R., Müllen, K.·2010·Journal of Physical Organic Chemistry

Abstract

Polycyclic aromatic hydrocarbons (PAHs) are popular research subjects due to their high stability, their rigid planar structure, and their characteristic optical spectra. The recent discovery of graphene, which can be regarded as giant PAH, has further stimulated the interest in this area. For this reason, the relationship between the geometric and electronic structure and the optical spectra of PAHs are reviewed, pointing out the versatile properties of this class of molecules. Extremely stable fully‐benzenoid PAHs with high optical gaps are encountered on the one side and the very reactive acenes with low optical gaps on the other side. A huge range of molecular sizes is covered from the simplest case benzene with its six carbon atoms up to disks containing as much as 96 carbon atoms. Furthermore, the impact of non‐planarity is discussed as model cases for the highly important fullerenes and carbon nanotubes. The detailed analysis of the electronic structure of PAHs is very important with regard to their application as fluorescent dyes or organic semiconductors. The presented research results shall encourage developments of new PAH structures to exploit novel materials properties. Copyright © 2010 John Wiley & Sons, Ltd.

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Metadata

Authors
Rieger, R., & Müllen, K.
Venue
Journal of Physical Organic Chemistry
Publisher
Wiley
Published
2010-03-24
Volume
23
Issue
4
Pages
315-325
ISSN
  • 0894-3230 (ISSN-L)
  • 1099-1395
OpenAlex
W1988382080
Cited by
446
References
61
FWCI
8.52
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Forever young: polycyclic aromatic hydrocarbons as model cases for structural and optical studies. https://app.cochat.ai/papers/10.1002/poc.1644
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Rieger, R., & Müllen, K. (2010). Forever young: polycyclic aromatic hydrocarbons as model cases for structural and optical studies. Journal of Physical Organic Chemistry. https://doi.org/10.1002/poc.1644

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