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Cited by 479

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The general theory of irreversible processes in solutions of macromolecules

Kirkwood, John G.·1954·Journal of Polymer Science

Abstract

The general theory of irreversible processes in solutions of macromolecules, previously formulated by the author, is reviewed. The theory is based upon the Oseen method for determining the perturbation in the hydrodynamic flow pattern produced by the frictional forces exerted by the macromolecule on the solvent, and on a generalized theory of Brownian motion in molecular configuration space. Applications of theory to viscoelastic behavior, flow birefringence, and the Kerr effect, and to dielectric dispersion are presented in outline.

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Metadata

Authors
Kirkwood, J. G.
Venue
Journal of Polymer Science
Publisher
Wiley
Published
1954-01
Volume
12
Issue
1
Pages
1-14
ISSN
  • 0022-3832 (ISSN-L)
  • 1542-6238
OpenAlex
W2071506921
Cited by
479
References
0
FWCI
7.82
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The general theory of irreversible processes in solutions of macromolecules. https://app.cochat.ai/papers/10.1002/pol.1954.120120102
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Kirkwood, J. G. (1954). The general theory of irreversible processes in solutions of macromolecules. Journal of Polymer Science. https://doi.org/10.1002/pol.1954.120120102

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.