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Copolymers in dilute solution. I. Preliminary results for styrene‐methyl methacrylate
Abstract
The dilute solution properties of copolymers are briefly discussed in relation to those of the parent homopolymers. It is shown that copolymer molecules are usually more expanded in solution than would be expected from the averaged behavior of the pure polymers, because of repulsive interactions between the unlike monomer units. A thermodynamic parameter χAB characterizing these interactions can be derived from measurements of the dilute solution properties of copolymers. In favorable cases this parameter can be independently evaluated from studies of ternary systems composed of the two parent homopolymers and a solvent, thus allowing prediction of the behavior of the copolymer. Light scattering and viscosity measurements on fractions of approximately equimolal copolymers of styrene and methyl methacrylate are presented and analyzed. The values of χAB deduced from the results in two solvents agree satisfactorily with each other, but are somewhat larger than those earlier obtained from measurements on ternary systems.
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Cites
Principles of polymer chemistry
Oster, G. (1954) · Journal of Chemical Education · doi:10.1021/ed031p669.2 · Cited by 2,503
The solubility of nonelectrolytes
Myerson, A. L. (1951) · Journal of the Franklin Institute · doi:10.1016/0016-0032(51)90518-2 · Cited by 2,333
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Zimm, B. H. (1946) · The Journal of Chemical Physics · doi:10.1063/1.1724116 · Cited by 387
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Phase separation in polymer solution
Dobry, A., & Boyer‐Kawenoki, F. (1947) · Journal of Polymer Science · doi:10.1002/pol.1947.120020111 · Cited by 324
Thermodynamics of high polymer solutions. VI. The compatibility of copolymers
Scott, R. L. (1952) · Journal of Polymer Science · doi:10.1002/pol.1952.120090504 · Cited by 132
Cited by
Light scattering and the absolute characterization of macromolecules
Wyatt, P. J. (1993) · Analytica Chimica Acta · doi:10.1016/0003-2670(93)80373-s · Cited by 1,436
Static and dynamic light scattering from branched polymers and biopolymers
Burchard, W. (2007) · Advances in Polymer Science · doi:10.1007/3-540-12030-0_1 · Cited by 697
Block Copolymers: Past Successes and Future Challenges
Lodge, T. P. (2003) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200290073 · Cited by 567
Chain Segregation in Block Copolymers
Brown, R. A., Masters, A. J., Price, C., & Yuan, X. F. (1989) · Comprehensive Polymer Science and Supplements · doi:10.1016/b978-0-08-096701-1.00043-4 · Cited by 23
Erlebach, A., Ott, T., Otzen, C., Schubert, S., Czaplewska, J., Schubert, U. S., & Sierka, M. (2016) · Journal of Computational Chemistry · doi:10.1002/jcc.24449 · Cited by 18
Metadata
- Authors
- Stockmayer, W. H., Moore, L. D., Fixman, M., & Epstein, B. N.
- Venue
- Journal of Polymer Science
- Publisher
- Wiley
- Published
- 1955-04
- Volume
- 16
- Issue
- 82
- Pages
- 517-530
- ISSN
- 0022-3832 (ISSN-L)
- 1542-6238
- OpenAlex
- W2022016244
- Cited by
- 314
- References
- 9
- FWCI
- 2.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Stockmayer, W. H., Moore, L. D., Fixman, M., & Epstein, B. N. (1955). Copolymers in dilute solution. I. Preliminary results for styrene‐methyl methacrylate. Journal of Polymer Science. https://doi.org/10.1002/pol.1955.120168236
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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