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Nuclear magnetic resonance study of rubber–carbon black interactions
Abstract
The mobilities of polymer chain segments in mixtures of rubber and carbon black were investigated by nuclear magnetic resonance. Spin–spin relaxation time (T2) measurements on cis‐polybutadiene and ethylene–propylene–diene rubber (EPDM) bound rubbers detected at least two relaxing regions: an immobile region and a relatively free region. The molecular motions in the relatively free region are still constrained compared to those of the pure gum.
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Citations
Cited by
Robertson, C. G., Lin, C. J., Rackaitis, M., & Roland, C. M. (2008) · Macromolecules · doi:10.1021/ma7022364 · Cited by 316
Merabia, S., Sotta, P., & Long, D. R. (2008) · Macromolecules · doi:10.1021/ma8014728 · Cited by 284
Recent advances in the NMR of solid polymers
McBrierty, V. J., & Douglass, D. C. (1981) · Journal of Polymer Science: Macromolecular Reviews · doi:10.1002/pol.1981.230160105 · Cited by 271
Low-field NMR investigations of nanocomposites: Polymer dynamics and network effects
Papon, A., Saalwächter, K., Schäler, K., Guy, L., Lequeux, F., & Montes, H. (2011) · Macromolecules · doi:10.1021/ma102486x · Cited by 267
Montes, H., Lequeux, F., & Berriot, J. (2003) · Macromolecules · doi:10.1021/ma0344590 · Cited by 189
Metadata
- Authors
- Kaufman, S., Slichter, W. P., & Davis, D. D.
- Venue
- Journal of Polymer Science Part A-2: Polymer Physics
- Publisher
- Wiley
- Published
- 1971-05
- Volume
- 9
- Issue
- 5
- Pages
- 829-839
- ISSN
- 0449-2978 (ISSN-L)
- 1542-9377
- OpenAlex
- W2102720416
- Cited by
- 180
- References
- 0
- FWCI
- 1.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Nuclear magnetic resonance study of rubber–carbon black interactions. https://app.cochat.ai/papers/10.1002/pol.1971.160090505
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- Kaufman, S., Slichter, W. P., & Davis, D. D. (1971). Nuclear magnetic resonance study of rubber–carbon black interactions. Journal of Polymer Science Part A-2: Polymer Physics. https://doi.org/10.1002/pol.1971.160090505
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