The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Anionic polymerization of propylene oxide: Isomerization of allyl ether to propenyl ether end groups
Abstract
Abstract The isomerization of allyl ether to propenyl ether end group in anionically‐polymerized poly (propylene oxide) was monitored by 1H NMR spectroscopy. It was confirmed that the reaction followed a simple second‐order rate law: −d[allyl]dt = k2[allyl] [O−]. Values of k2 determined over the 90–130°C temperature range, indicated an activation energy of 116 kJ mol−1. © 1994 John Wiley & Sons, Inc.
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“The extensive chain transfer to monomer, typical of substituted oxiranes prohibits the formation of high polymers [117]”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [117]
Citations
Cites
SOLVENT EFFECTS IN THE BASE-CATALYZED ISOMERIZATION OF ALLYL TO PROPENYL ETHERS
Price, C. C., & Snyder, W. H. (1961) · Journal of the American Chemical Society · doi:10.1021/ja01468a062 · Cited by 152
The polymerization of propylene oxide
Simons, D. M., & Verbanc, J. J. (1960) · Journal of Polymer Science · doi:10.1002/pol.1960.1204414403 · Cited by 119
A Study of the Polymerization of Propylene Oxide Catalyzed by Anhydrous Potassium Hydroxide
Steiner, E. C., Pelletier, R. R., & Trucks, R. O. (1964) · Journal of the American Chemical Society · doi:10.1021/ja01075a031 · Cited by 118
Solvation and ion pairing of alkali-metal alkoxides in dimethyl sulfoxide. Conductometric studies
Exner, J. H., & Steiner, E. C. (1974) · Journal of the American Chemical Society · doi:10.1021/ja00813a022 · Cited by 110
Price, C. C. (1974) · Accounts of Chemical Research · doi:10.1021/ar50081a003 · Cited by 71
Polypropylene oxide III—Crystallizability, fusion and glass formation
Allen, G., Booth, C., Jones, M. N., Marks, D. J., & Taylor, W. D. (1964) · Polymer · doi:10.1016/0032-3861(64)90205-8 · Cited by 40
Self-citationBecker, H., Wagner, G. H., & Stolarzewicz, A. (1982) · Acta Polymerica · doi:10.1002/actp.1982.010330107 · Cited by 34
Sandell, L. S., & Goring, D. A. I. (1970) · Macromolecules · doi:10.1021/ma60013a011 · Cited by 19
Becker, H., Wagner, G. H., & Stolarzewicz, A. (1981) · Acta Polymerica · doi:10.1002/actp.1981.010321207 · Cited by 15
Stolarzewicz, A., Becker, H., & Wagner, G. H. (1981) · Acta Polymerica · doi:10.1002/actp.1981.010320811 · Cited by 14
Cited by
Ring-Opening Polymerization—An Introductory Review
Nuyken, O., & Pask, S. (2013) · Polymers · doi:10.3390/polym5020361 · Cited by 456
Trends in industrial catalysis in the polyurethane industry
Wegener, G., Brandt, M., Duda, L., Hofmann, J., Klesczewski, B., Koch, D., Kumpf, R.-J., Orzesek, H., Pirkl, H., Six, C., et al. (2001) · Applied Catalysis A General · doi:10.1016/s0926-860x(01)00910-3 · Cited by 237
Thermodynamics and Kinetics of Ring‐Opening Polymerization
Duda, A., & Kowalski, A. (2009) · Wiley eBooks · doi:10.1002/9783527628407.ch1 · Cited by 134
Poly(allyl glycidyl ether)‐A versatile and functional polyether platform
Lee, B. F., Kade, M. J., Chute, J. A., Gupta, N., Campos, L. M., Fredrickson, G. H., Krämer, E. J., Lynd, N. A., & Hawker, C. J. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24891 · Cited by 122
Malik, M. I., Trathnigg, B., & Kappe, C. O. (2007) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200700320 · Cited by 42
Metadata
- Authors
- Yu, G., Heatley, F., Booth, C., & Blease, T. G.
- Affiliations
- University of Manchester (GB)
- Corresponding author
- Booth, Colin
- Venue
- Journal of Polymer Science Part A: Polymer Chemistry
- Publisher
- Wiley
- Published
- 1994-04-30
- Volume
- 32
- Issue
- 6
- Pages
- 1131-1135
- ISSN
- 0887-624X (ISSN-L)
- 1099-0518
- OpenAlex
- W1973744148
- Cited by
- 36
- References
- 10
- Citations by year
- 2026: 1 · 2025: 1 · 2022: 2 · 2021: 4 · 2020: 1 · 2019: 1 · 2018: 2 · 2017: 2 · 2016: 3 · 2015: 1 · 2014: 1 · 2013: 2
- FWCI
- 0.62
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Polymer Science Part A Polymer Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- anionic polymerization, propylene oxide, polypropylene glycol, allyl ethers, second-order kinetics, activation energy, 1H NMR monitoring
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- The paper
- Yu, G., Heatley, F., Booth, C., & Blease, T. G. (1994). Anionic polymerization of propylene oxide: Isomerization of allyl ether to propenyl ether end groups. Journal of Polymer Science Part A: Polymer Chemistry. https://doi.org/10.1002/pola.1994.080320615
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
