The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Covalent bonded polymer–graphene nanocomposites
Abstract
This report describes a new route to covalently bonded polymer–graphene nanocomposites and the subsequent enhancement in thermal and mechanical properties of the resultant nanocomposites. At first, the graphite is oxidized by the modified Hummers method followed by functionalization with Octadecylamine (ODA). The ODA functionalized graphite oxides are reacted with methacryloyl chloride to incorporate polymerizable CC functionality at the nanographene platelet surfaces, which were subsequently employed in in situ polymerization of methylmethacrylate to obtain covalently bonded poly(methyl methacrylate) (PMMA)–graphene nanocomposites. The obtained nanocomposites show significant enhancement in thermal and mechanical properties compared with neat PMMA. Thus, even with 0.5 wt % graphene nanosheets, the Tg increased from 119 °C for neat PMMA to 131 °C for PMMA–graphene nanocomposite, and the respective storage modulus increased from 1.29 to 2 GPa. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 4262–4267, 2010
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Citations
Cites
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Cited by
Graphene-based polymer nanocomposites
Potts, J. R., Dreyer, D. R., Bielawski, C. W., & Ruoff, R. S. (2011) · Polymer · doi:10.1016/j.polymer.2010.11.042 · Cited by 3,123
Bao, C., Song, L., Xing, W., Yuan, B., Wilkie, C. A., Huang, J., Guo, Y., & Hu, Y. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm16203b · Cited by 406
Epoxy Toughening with Low Graphene Loading
Park, Y. T., Qian, Y., Chan, C., Suh, T., Nejhad, M. G., Macosko, C. W., & Stein, A. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201402553 · Cited by 362
Recent Advances in the Covalent Modification of Graphene With Polymers
Salavagione, H. J., Martínez, G., & Ellis, G. (2011) · Macromolecular Rapid Communications · doi:10.1002/marc.201100527 · Cited by 295
Wang, J.-Y., Yang, S.-Y., Huang, Y.-L., Tien, H.-W., Chin, W.-K., & Ma, C.-C. M. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm11766a · Cited by 288
Metadata
- Authors
- Pramoda, K. P., Hussain, H., Koh, H. M., Tan, H. R., & He, C. B.
- Venue
- Journal of Polymer Science Part A: Polymer Chemistry
- Publisher
- Wiley
- Published
- 2010-08-24
- Volume
- 48
- Issue
- 19
- Pages
- 4262-4267
- ISSN
- 0887-624X (ISSN-L)
- 1099-0518
- OpenAlex
- W1995645748
- Cited by
- 177
- References
- 1
- FWCI
- 14.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pramoda, K. P., Hussain, H., Koh, H. M., Tan, H. R., & He, C. B. (2010). Covalent bonded polymer–graphene nanocomposites. Journal of Polymer Science Part A: Polymer Chemistry. https://doi.org/10.1002/pola.24212
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