The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Facile fabrication of fast recyclable and multiple self‐healing epoxy materials through diels‐alder adduct cross‐linker
Abstract
A reversibly cross‐linked epoxy resin with efficient reprocessing and intrinsic self‐healing was prepared from a diamine Diels‐Alder (DA) adduct cross‐linker and a commercial epoxy oligomer. The newly synthesized diamine cross‐linker, comprising a DA adduct of furan and maleimide moieties, can cure epoxy monomer/oligomer with thermal reversibility. The reversible transition between cross‐linked state and linear architecture endows the cured epoxy with rapid recyclability and repeated healability. The reversibly cross‐linked epoxy fundamentally behaves as typical thermosets at ambient conditions yet can be fast reprocessed at elevated temperature like thermoplastics. As a potential reversible adhesive, the epoxy polymer with adhesive strength values about 3 MPa showed full recovery after repeated fracture‐thermal healing processes. The methodology explored in this contribution provides new insights in modification of conventional engineering plastics as functional materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 2094–2103
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Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
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Advances in 4D Printing: Materials and Applications
Kuang, X., Roach, D. J., Wu, J., Hamel, C. M., Ding, Z., Wang, T., Dunn, M. L., & Qi, H. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201805290 · Cited by 1,095
Self-citation3D Printing of Highly Stretchable, Shape-Memory, and Self-Healing Elastomer toward Novel 4D Printing
Kuang, X., Chen, K., Dunn, C. K., Wu, J., Li, V. C. F., & Qi, H. J. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b18265 · Cited by 523
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Metadata
- Authors
- Kuang, X., Liu, G., Dong, X., Liu, X., Xu, J., & Wang, D.
- Venue
- Journal of Polymer Science Part A: Polymer Chemistry
- Publisher
- Wiley
- Published
- 2015-04-11
- Volume
- 53
- Issue
- 18
- Pages
- 2094-2103
- ISSN
- 0887-624X (ISSN-L)
- 1099-0518
- OpenAlex
- W2096963933
- Cited by
- 181
- References
- 1
- FWCI
- 8.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kuang, X., Liu, G., Dong, X., Liu, X., Xu, J., & Wang, D. (2015). Facile fabrication of fast recyclable and multiple self‐healing epoxy materials through diels‐alder adduct cross‐linker. Journal of Polymer Science Part A: Polymer Chemistry. https://doi.org/10.1002/pola.27655
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