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New poly(butylene succinate)/layered silicate nanocomposites. II. Effect of organically modified layered silicates on structure, properties, melt rheology, and biodegradability
Abstract
A series of new poly(butylene succinate) (PBS)/layered silicate nanocomposites were prepared successfully by simple melt extrusion of PBS and organically modified layered silicates (OMLS). Three different types of OMLS were used for the preparation of nanocomposites: two functionalized ammonium salts modified montmorillonite and a phosphonium salt modified saponite. The structure of the nanocomposites in the nanometer scale was characterized with wide‐angle X‐ray diffraction and transmission electron microscopic observations. With three different types of layered silicates modified with three different types of surfactants, the effect of OMLS in nanocomposites was investigated by focusing on four major aspects: structural analysis, materials properties, melt rheological behavior, and biodegradability. Interestingly, all these nanocomposites exhibited concurrent improvements of material properties when compared with pure PBS. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 3160–3172, 2003
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Cites
New polylactide/layered silicate nanocomposites. 1. Preparation, characterization, and properties
Sinha Ray, S., Maiti, P., Okamoto, M., Yamada, K., & Ueda, K. (2002) · Macromolecules · doi:10.1021/ma011613e · Cited by 607
Self-citationNew polylactide/layered silicate nanocomposites. 5. Designing of materials with desired properties
Sinha Ray, S., Yamada, K., Okamoto, M., Fujimoto, Y., Ogami, A., & Ueda, K. (2003) · Polymer · doi:10.1016/j.polymer.2003.08.021 · Cited by 317
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SINHARAY, S., & BOUSMINA, M. (2005) · Progress in Materials Science · doi:10.1016/j.pmatsci.2005.05.002 · Cited by 1,611
Self-citationNano-biocomposites: Biodegradable polyester/nanoclay systems
BORDES, P., POLLET, E., & AVEROUS, L. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2008.10.002 · Cited by 1,033
Metadata
- Authors
- Okamoto, K., Sinha Ray, S., & Okamoto, M.
- Venue
- Journal of Polymer Science Part B: Polymer Physics
- Publisher
- Wiley
- Published
- 2003-11-11
- Volume
- 41
- Issue
- 24
- Pages
- 3160-3172
- ISSN
- 0887-6266 (ISSN-L)
- 1099-0488
- OpenAlex
- W2128000645
- Cited by
- 164
- References
- 2
- FWCI
- 5.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Okamoto, K., Sinha Ray, S., & Okamoto, M. (2003). New poly(butylene succinate)/layered silicate nanocomposites. II. Effect of organically modified layered silicates on structure, properties, melt rheology, and biodegradability. Journal of Polymer Science Part B: Polymer Physics. https://doi.org/10.1002/polb.10708
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