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Elastic modulus of the crystalline regions of cellulose polymorphs
Abstract
The elastic modulus E l of the crystalline regions of cellulose polymorphs in the direction parallel to the chain axis was measured by x‐ray diffraction. The E l values of cellulose I, II, III I, III II, and IV I were 138, 88, 87, 58, 75 GPa, respectively. This indicates that the skeletons of these polymorphs are completely different from each other in the mechanical point of view. The crystal transition induces a skeletal contraction accompanied by a change in intramolecular hydrogen bonds, which is considered to result in a drastic change in the E l value of the cellulose polymorphs. © 1995 John Wiley & Sons, Inc.
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Citations
Cites
Experimental determination of the elastic modulus of crystalline regions in oriented polymers
Sakurada, I., Nukushina, Y., & Ito, T. (1962) · Journal of Polymer Science · doi:10.1002/pol.1962.1205716551 · Cited by 883
Cited by
Elastic modulus of single cellulose microfibrils from tunicate measured by atomic force microscopy
Iwamoto, S., Kai, W., Isogai, A., & Iwata, T. (2009) · Biomacromolecules · doi:10.1021/bm900520n · Cited by 754
Cellulose and the role of hydrogen bonds: not in charge of everything
Wohlert, M., Benselfelt, T., Wågberg, L., Furó, I., Berglund, L. A., & Wohlert, J. (2022) · Cellulose · doi:10.1007/s10570-021-04325-4 · Cited by 580
Structure and properties of the cellulose microfibril
Nishiyama, Y. (2009) · Journal of Wood Science · doi:10.1007/s10086-009-1029-1 · Cited by 567
Nanocomposites of cellulose acetate butyrate reinforced with cellulose nanocrystals
Grunert, M., & Winter, W. T. (2002) · Journal of Polymers and the Environment · doi:10.1023/a:1021065905986 · Cited by 465
Cellulose Nanofiber Orientation in Nanopaper and Nanocomposites by Cold Drawing
Sehaqui, H., Ezekiel Mushi, N., Morimune, S., Salajkova, M., Nishino, T., & Berglund, L. A. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am2016766 · Cited by 351
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Metadata
- Authors
- Nishino, T., Takano, K., & Nakamae, K.
- Venue
- Journal of Polymer Science Part B: Polymer Physics
- Publisher
- Wiley
- Published
- 1995-08
- Volume
- 33
- Issue
- 11
- Pages
- 1647-1651
- ISSN
- 0887-6266 (ISSN-L)
- 1099-0488
- OpenAlex
- W2032325148
- Cited by
- 581
- References
- 1
- FWCI
- 2.70
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nishino, T., Takano, K., & Nakamae, K. (1995). Elastic modulus of the crystalline regions of cellulose polymorphs. Journal of Polymer Science Part B: Polymer Physics. https://doi.org/10.1002/polb.1995.090331110
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
