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Mechanical properties of crystalline calcium‐silicate‐hydrates: comparison with cementitious C‐S‐H gels
Abstract
This work explores from a theoretical viewpoint the mechanical properties of the most important hydration product present in cementitious environments, the so called C‐S‐H (calcium‐silicate‐hydrate) gel. The dependence of the bulk (K), shear (G) and Young's (E) modulus for the C‐S‐H crystals respect to its composition and the length of its silicate chains is analysed by lattice dynamic simulations with parameterised two‐body and three‐body potentials. Our simulations reveal that the mechanical properties of C‐S‐H crystals show a strong dependence on their composition. Nevertheless our calculated numbers systematically overestimate the experimental values for C‐S‐H gels. Only when the finite length of the silicate chains is taken into account this discrepancy disappears. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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Cited by
27 Al and 29 Si Solid-State NMR Characterization of Calcium-Aluminosilicate-Hydrate
Pardal, X., Brunet, F., Charpentier, T., Pochard, I., & Nonat, A. (2012) · Inorganic Chemistry · doi:10.1021/ic202124x · Cited by 328
Elastic properties of the main species present in Portland cement pastes
Manzano, H., Dolado, J. S., & Ayuela, A. (2009) · Acta Materialia · doi:10.1016/j.actamat.2008.12.007 · Cited by 277
Self-citationGrangeon, S., Fernandez-Martinez, A., Baronnet, A., Marty, N., Poulain, A., Elkaïm, E., Roosz, C., Gaboreau, S., Henocq, P., & Claret, F. (2017) · Journal of Applied Crystallography · doi:10.1107/s1600576716017404 · Cited by 103
Metadata
- Authors
- Manzano, H., Dolado, J. S., Guerrero, A., & Ayuela, A.
- Venue
- physica status solidi (a)
- Publisher
- Wiley
- Published
- 2007-05-31
- Volume
- 204
- Issue
- 6
- Pages
- 1775-1780
- ISSN
- 0031-8965 (ISSN-L)
- 1862-6300
- 1862-6319
- OpenAlex
- W2138384979
- Cited by
- 158
- References
- 0
- FWCI
- 20.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Manzano, H., Dolado, J. S., Guerrero, A., & Ayuela, A. (2007). Mechanical properties of crystalline calcium‐silicate‐hydrates: comparison with cementitious C‐S‐H gels. physica status solidi (a). https://doi.org/10.1002/pssa.200675359
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