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Infrared Absorption in Small Ionic Crystals
Abstract
The infrared transmission of 0.1 μm crystals of MgO has been measured in the region of fundamental lattice absorption. In particular, the effects of anharmonicity and particle density on the transmission have been observed. These effects have also been calculated using a continuum model applicable to spheres very much smaller than the wavelength of light. In agreement with these calculations, the frequency of the fundamental infrared absorption of small particles was found to decrease with increasing particle density. In addition, it was observed that the frequency dependent damping function of massive MgO must be increased by a factor of about eight in small crystals in order to fit the experimental data.
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Cites
Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
Mie, G. (1908) · Annalen der Physik · doi:10.1002/andp.19083300302 · Cited by 11,537
Cited by
Theory of the optical properties of ionic crystal cubes
Fuchs, R. (1975) · Physical Review B · doi:10.1103/physrevb.11.1732 · Cited by 396
Alkali halide clusters and microcrystals
Martin, T. P. (1983) · Physics Reports · doi:10.1016/0370-1573(83)90024-8 · Cited by 368
Self-citationThe challenge of ceramic/metal microcomposites and nanocomposites
Moya, J. S., Lopez-Esteban, S., & Pecharromán, C. (2007) · Progress in Materials Science · doi:10.1016/j.pmatsci.2006.09.003 · Cited by 358
Metal colloids in ionic crystals
Hughes, A. E., & Jain, S. C. (1979) · Advances in Physics · doi:10.1080/00018737900101445 · Cited by 318
Metadata
- Authors
- Genzel, L., & Martin, T. P.
- Venue
- physica status solidi (b)
- Publisher
- Wiley
- Published
- 1972-05
- Volume
- 51
- Issue
- 1
- Pages
- 91-99
- ISSN
- 0370-1972 (ISSN-L)
- 1521-3951
- OpenAlex
- W2116838717
- Cited by
- 192
- References
- 1
- FWCI
- 10.08
- Type
- journal article
- Language
- en
- Open access
- closed
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