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Small volume and low flow‐rate electrospray lonization mass spectrometry of aqueous samples
Open accessAbstract
A new electrospray ionization source (emitter) has been developed which allows the effective utilization of very small sample volumes at much lower flow rates than previously demonstrated. A small diameter etcched‐tip capillary has been incorporated into a pressure‐infusion electrospray ionization source. The ability to electro‐spray aqueous solutions without the use of an ancillary sheath flow is demonstrated with several biopolymers. High signal intensities and stable signals are observed for this source in a comparison with a standard methanol‐sheath source.
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Citations
Cited by
Mass Spectrometry, Review of the Basics: Electrospray, MALDI, and Commonly Used Mass Analyzers
El-Aneed, A., Cohen, A., & Banoub, J. (2009) · Applied Spectroscopy Reviews · doi:10.1080/05704920902717872 · Cited by 386
Recent advances in capillary electrophoresis/electrospray/mass spectrometry
Banks, J. F. (1997) · ELECTROPHORESIS · doi:10.1002/elps.1150181216 · Cited by 308
Capillary electrophoresis – mass spectrometry: 15 years of developments and applications
Schmitt‐Kopplin, P., & Frommberger, M. (2003) · ELECTROPHORESIS · doi:10.1002/elps.200305659 · Cited by 289
The ion funnel: Theory, implementations, and applications
Kelly, R. T., Tolmachev, A. V., Page, J. S., Tang, K., & Smith, R. D. (2010) · Mass Spectrometry Reviews · doi:10.1002/mas.20232 · Cited by 280
Self-citationKammeijer, G. S. M., Kohler, I., Jansen, B. C., Hensbergen, P. J., Mayboroda, O. A., Falck, D., & Wuhrer, M. (2016) · Analytical Chemistry · doi:10.1021/acs.analchem.6b00479 · Cited by 74
Metadata
- Authors
- Gale, D. C., & Smith, R. D.
- Venue
- Rapid Communications in Mass Spectrometry
- Publisher
- Wiley
- Published
- 1993-11
- Volume
- 7
- Issue
- 11
- Pages
- 1017-1021
- ISSN
- 0951-4198 (ISSN-L)
- 1097-0231
- OpenAlex
- W2057954468
- Cited by
- 176
- References
- 0
- FWCI
- 7.03
- Type
- journal article
- Language
- en
- Open access
- green
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- Gale, D. C., & Smith, R. D. (1993). Small volume and low flow‐rate electrospray lonization mass spectrometry of aqueous samples. Rapid Communications in Mass Spectrometry. https://doi.org/10.1002/rcm.1290071111
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