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The theory of measurement of osmotic pressure
Abstract
Application of Onsager's symmetry relations to the process of diffusion of a solution through a membrane shows that measured osmotic pressures deviate from those calculated thermodynamically in proportion to the permeability of the membrane to the solute molecules. Therefore little is learned from one dynamic osmotic measurement but by simultaneous measurements of osmotic pressure and permeation at different membranes the entire molecular weight distribution of the solute can be computed.
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Citations
Cited by
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Levick, J. R., & Michel, C. C. (2010) · Cardiovascular Research · doi:10.1093/cvr/cvq062 · Cited by 1,183
Thermodynamics of hyperfiltration (reverse osmosis): criteria for efficient membranes
Spiegler, K. S., & Kedem, O. (1966) · Desalination · doi:10.1016/s0011-9164(00)80018-1 · Cited by 1,079
Mechanisms of fluid movement into, through and out of the brain: evaluation of the evidence
Hladky, S. B., & Barrand, M. A. (2014) · Fluids and Barriers of the CNS · doi:10.1186/2045-8118-11-26 · Cited by 633
A Model System for Biological Water Transport
CURRAN, P. F., & MACINTOSH, J. R. (1962) · Nature · doi:10.1038/193347a0 · Cited by 398
Membrane Permeability Modeling: Kedem–Katchalsky vs a Two-Parameter Formalism
Kleinhans, F. W. (1998) · Cryobiology · doi:10.1006/cryo.1998.2135 · Cited by 273
Metadata
- Authors
- Staverman, A. J.
- Venue
- Recueil des Travaux Chimiques des Pays-Bas
- Publisher
- Wiley
- Published
- 1951-01
- Volume
- 70
- Issue
- 4
- Pages
- 344-352
- ISSN
- 0165-0513 (ISSN-L)
- OpenAlex
- W1987066032
- Cited by
- 547
- References
- 0
- FWCI
- 8.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: The theory of measurement of osmotic pressure. https://app.cochat.ai/papers/10.1002/recl.19510700409
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- Staverman, A. J. (1951). The theory of measurement of osmotic pressure. Recueil des Travaux Chimiques des Pays-Bas. https://doi.org/10.1002/recl.19510700409
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
