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Macroscopic Fibers of Well‐Aligned Carbon Nanotubes by Wet Spinning
Abstract
A simple process to spin fibers consisting of multi‐walled carbon nanotubes (CNTs) directly from their lyotropic liquid‐crystalline phase is reported. Ethylene glycol is used as the lyotropic solvent, enabling a wider range of CNT types to be spun than previously. Fibers spun with CNTs and nitrogen‐doped CNTs are compared. X‐ray analysis reveals that nitrogen‐doped CNTs have a misalignment of only ±7.8° to the fiber axis. The tensile strength of the CNT and nitrogen‐doped CNT fibers is comparable but the modulus and electrical conductivity of the are lower. The electrical conductivity of both types of CNT fibers is found to be highly anisotropic. The results are discussed in context of the microstructure of the CNTs and fibers.
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Cited by
True solutions of single-walled carbon nanotubes for assembly into macroscopic materials
Davis, V. A., Parra-Vasquez, A. N. G., Green, M. J., Rai, P. K., Behabtu, N., Prieto, V., Booker, R. D., Schmidt, J., Kesselman, E., Zhou, W., et al. (2009) · Nature Nanotechnology · doi:10.1038/nnano.2009.302 · Cited by 559
Superstructured Assembly of Nanocarbons: Fullerenes, Nanotubes, and Graphene
Li, Z., Liu, Z., Sun, H., & Gao, C. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00102 · Cited by 554
Macroscopic Carbon Nanotube Assemblies: Preparation, Properties, and Potential Applications
Liu, L., Ma, W., & Zhang, Z. (2011) · Small · doi:10.1002/smll.201002198 · Cited by 323
Functional Fiber Materials to Smart Fiber Devices
Chen, C., Feng, J., Li, J., Guo, Y., Shi, X., & Peng, H. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00192 · Cited by 308
Carbon nanotubes in liquid crystals
Lagerwall, J. P. F., & Scalia, G. (2008) · Journal of Materials Chemistry · doi:10.1039/b802707b · Cited by 278
Metadata
- Authors
- Zhang, S., Koziol, K. K. K., Kinloch, I. A., & Windle, A. H.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2008-07-31
- Volume
- 4
- Issue
- 8
- Pages
- 1217-1222
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2116209222
- Cited by
- 181
- References
- 0
- FWCI
- 4.04
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, S., Koziol, K. K. K., Kinloch, I. A., & Windle, A. H. (2008). Macroscopic Fibers of Well‐Aligned Carbon Nanotubes by Wet Spinning. Small. https://doi.org/10.1002/smll.200700998
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