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Cited by 455

The DOI matches its Crossref record; 71 of the 71 references it cites were found in a registry or an index.

A Novel Application of Plasmonics: Plasmon‐Driven Surface‐Catalyzed Reactions

Sun, Mengtao, Xu, Hongxing·2012·Small

Abstract

The first experimental and theoretical evidence of the surface‐catalyzed reaction of p,p′‐dimercaptoazobenzene (DMAB) produced from para‐aminothiophenol (PATP) by local surface plasmons was reported in 2010, and since that time a series of investigations have supported these findings using different experimental and theoretical methods. Recent work has also found that local plasmons can drive a surface‐catalyzed reaction of DMAB converted from 4‐nitrobenzenethiol (4NBT), assisted by local surface plasmons. There are at least three important discoveries in these investigations: 1) in the field of surface‐enhanced Raman scattering (SERS) the widely accepted misinterpretation (since 1994) that the chemical mechanism resulting in three additional Raman peaks of PATP in Ag or Au solutions has been corrected with a new mechanism; 2) it is confirmed that SERS is not always a noninvasive technique, and under certain conditions cannot always obtain the vibrational fingerprint information of the original surface species; 3) a novel method to synthesize new molecules, induced by local surface plasmons or plasmon waveguides on the nanoscale, has been found. This Review considers recent novel applications of plasmonics to chemical reactions, especially to plasmon‐driven surface‐catalyzed reactions.

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Metadata

Authors
Sun, M., & Xu, H.
Venue
Small
Publisher
Wiley
Published
2012-07-06
Volume
8
Issue
18
Pages
2777-2786
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
OpenAlex
W2130178945
Cited by
455
References
71
FWCI
17.61
Type
journal article
Language
en
Open access
closed

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Sun, M., & Xu, H. (2012). A Novel Application of Plasmonics: Plasmon‐Driven Surface‐Catalyzed Reactions. Small. https://doi.org/10.1002/smll.201200572

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