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Synthesis and Photocatalytic Application of Stable Lead‐Free Cs2AgBiBr6 Perovskite Nanocrystals
Abstract
Lead halide perovskite nanocrystals (NCs) have demonstrated great potential as appealing candidates for advanced optoelectronic applications. However, the toxicity of lead and the intrinsic instability toward moisture hinder their mass production and commercialization. Herein, to solve such thorny problems, novel lead‐free Cs 2 AgBiBr 6 double perovskite NCs fabricated via a simple hot‐injection method are reported, which exhibit impressive stability in moisture, light, and temperature. Such materials are then applied into photocatalytic CO 2 reduction, achieving a total electron consumption of 105 µ mol g−1 under AM 1.5G illumination for 6 h. This study offers a reliable avenue for Cs 2 AgBiBr 6 perovskite nanocrystals preparation, which holds a great potential in the further photochemical applications.
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Cites
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Strongly emissive perovskite nanocrystal inks for high-voltage solar cells
Akkerman, Q. A., Gandini, M., Di Stasio, F., Rastogi, P., Palazon, F., Bertoni, G., Ball, J. M., Prato, M., Petrozza, A., & Manna, L. (2016) · Nature Energy · doi:10.1038/nenergy.2016.194 · Cited by 721
Cited by
Wei, Y., Cheng, Z., & Lin, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00740c · Cited by 1,206
Rational Design of Halide Double Perovskites for Optoelectronic Applications
Zhao, X.-G., Yang, D., Ren, J.-C., Sun, Y., Xiao, Z., & Zhang, L. (2018) · Joule · doi:10.1016/j.joule.2018.06.017 · Cited by 508
Semiconductor Quantum Dots: An Emerging Candidate for CO2 Photoreduction
Wu, H., Li, X., Tung, C., & Wu, L. (2019) · Advanced Materials · doi:10.1002/adma.201900709 · Cited by 486
Double Perovskites in Catalysis, Electrocatalysis, and Photo(electro)catalysis
Xu, X., Zhong, Y., & Shao, Z. (2019) · Trends in Chemistry · doi:10.1016/j.trechm.2019.05.006 · Cited by 367
Mn2+‐Doped Metal Halide Perovskites: Structure, Photoluminescence, and Application
Su, B., Zhou, G., Huang, J., Song, E., Nag, A., & Xia, Z. (2021) · Laser & Photonics Reviews · doi:10.1002/lpor.202000334 · Cited by 319
Metadata
- Authors
- Zhou, L., Xu, Y., Chen, B., Kuang, D., & Su, C.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2018-01-30
- Volume
- 14
- Issue
- 11
- Pages
- e1703762-e1703762
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2791738097
- Cited by
- 581
- References
- 2
- FWCI
- 23.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhou, L., Xu, Y., Chen, B., Kuang, D., & Su, C. (2018). Synthesis and Photocatalytic Application of Stable Lead‐Free Cs2AgBiBr6 Perovskite Nanocrystals. Small. https://doi.org/10.1002/smll.201703762
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