The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
ZIF‐8 with Ferrocene Encapsulated: A Promising Precursor to Single‐Atom Fe Embedded Nitrogen‐Doped Carbon as Highly Efficient Catalyst for Oxygen Electroreduction
Abstract
The oxygen reduction reaction (ORR) plays an important role in the fields of energy storage and conversion technologies, including metal–air batteries and fuel cells. The development of nonprecious metal electrocatalysts with both high ORR activity and durability to replace the currently used costly Pt‐based catalyst is critical and still a major challenge. Herein, a facile and scalable method is reported to prepare ZIF‐8 with single ferrocene molecules trapped within its cavities (Fc@ZIF‐8), which is utilized as precursor to porous single‐atom Fe embedded nitrogen‐doped carbon (Fe–N–C) during high temperature pyrolysis. The catalyst shows a half‐wave potential (E1/2) of 0.904 V, 67 mV higher than commercial Pt/C catalyst (0.837 V), which is among the best compared with reported results for ORR. Significant electrochemical properties are attributed to the special configuration of Fc@ZIF‐8 transforming into a highly dispersed iron–nitrogen coordination moieties embedded carbon matrix.
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Cites
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421
Cited by
Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications
Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 412
Highly Efficient Oxygen Reduction Reaction Activity of N‐Doped Carbon–Cobalt Boride Heterointerfaces
Jose, V., Nsanzimana, J. M. V., Hu, H., Choi, J., Wang, X., & Lee, J. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100157 · Cited by 294
Du, L., Xing, L., Zhang, G., Dubois, M., & Sun, S. (2020) · Small Methods · doi:10.1002/smtd.202000016 · Cited by 91
Self-citationEngineering of Nitrogen Coordinated Single Cobalt Atom Moieties for Oxygen Electroreduction
Sun, W., Du, L., Tan, Q., Zhou, J., Hu, Y., Du, C., Gao, Y., & Yin, G. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b11830 · Cited by 68
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Metadata
- Authors
- Wang, J., Han, G., Wang, L., Du, L., Chen, G., Gao, Y., Ma, Y., Du, C., Cheng, X., Zuo, P., & Yin, G.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2018-03-05
- Volume
- 14
- Issue
- 15
- Pages
- e1704282-e1704282
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2793009458
- Cited by
- 297
- References
- 2
- FWCI
- 8.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Wang, J., Han, G., Wang, L., Du, L., Chen, G., Gao, Y., Ma, Y., Du, C., Cheng, X., Zuo, P., & Yin, G. (2018). ZIF‐8 with Ferrocene Encapsulated: A Promising Precursor to Single‐Atom Fe Embedded Nitrogen‐Doped Carbon as Highly Efficient Catalyst for Oxygen Electroreduction. Small. https://doi.org/10.1002/smll.201704282
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