The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Red Phosphorus Nanoparticle@3D Interconnected Carbon Nanosheet Framework Composite for Potassium‐Ion Battery Anodes
Abstract
Red phosphorus (P) has been recognized as a promising storage material for Li and Na. However, it has not been reported for K storage and the reaction mechanism remains unknown. Herein, a novel nanocomposite anode material is designed and synthesized by anchoring red P nanoparticles on a 3D carbon nanosheet framework for K‐ion batteries (KIBs). The red P@CN composite demonstrates a superior electrochemical performance with a high reversible capacity of 655 mA h g−1 at 100 mA g−1 and a good rate capability remaining 323.7 mA h g−1 at 2000 mA g−1, which outperform reported anode materials for KIBs. The transmission electron microscopy and theoretical calculation results suggest a one‐electron reaction mechanism ofP + K+ + e−→ KP, corresponding to a theoretical capacity of 843 mA h g−1,which is the highest value for anode materials investigated for KIBs. The study not only sheds light on the rational design of high performance red P anodes for KIBs but also offers a fundamental understanding of the potassium storage mechanism of red P.
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Citations
Cites
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
About reactions occurring during chemical activation with hydroxides
Lillo-Ródenas, M. A., Juan-Juan, J., Cazorla-Amorós, D., & Linares-Solano, A. (2004) · Carbon · doi:10.1016/j.carbon.2004.01.008 · Cited by 389
Cited by
Tian, Y., Zeng, G., Rutt, A., Shi, T., Kim, H., Wang, J., Koettgen, J., Sun, Y., Ouyang, B., Chen, T., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00767 · Cited by 1,614
Advanced Carbon‐Based Anodes for Potassium‐Ion Batteries
Wu, X., Chen, Y., Xing, Z., Lam, C. W. K., Pang, S., Zhang, W., & Ju, Z. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201900343 · Cited by 600
Zheng, Z., Wu, H.-H., Liu, H., Zhang, Q., He, X., Yu, S., Petrova, V., Feng, J., Kostecki, R., Liu, P., et al. (2020) · ACS Nano · doi:10.1021/acsnano.9b08575 · Cited by 334
Dhir, S., Wheeler, S., Capone, I., & Pasta, M. (2020) · Chem · doi:10.1016/j.chempr.2020.08.012 · Cited by 293
Wu, Y., Hu, S., Xu, R., Wang, J., Peng, Z., Zhang, Q., & Yu, Y. (2019) · Nano Letters · doi:10.1021/acs.nanolett.8b04957 · Cited by 283
Metadata
- Authors
- Xiong, P., Bai, P., Tu, S., Cheng, M., Zhang, J., Sun, J., & Xu, Y.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2018-07-19
- Volume
- 14
- Issue
- 33
- Pages
- e1802140-e1802140
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2884268607
- Cited by
- 226
- References
- 2
- FWCI
- 14.58
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xiong, P., Bai, P., Tu, S., Cheng, M., Zhang, J., Sun, J., & Xu, Y. (2018). Red Phosphorus Nanoparticle@3D Interconnected Carbon Nanosheet Framework Composite for Potassium‐Ion Battery Anodes. Small. https://doi.org/10.1002/smll.201802140
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