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Cited by 32Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsCatalytic Processes in Materials Science

High‐Energy Facet Engineering for Electrocatalytic Applications

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Wang, Rui, Lee, Jong‐Min·2024·Small
DOI 10.1002/smll.202401546
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Abstract

The design of high‐energy facets in electrocatalysts has attracted significant attention due to their potential to enhance electrocatalytic activity. In this review, the significance of high‐energy facets in various electrochemical reactions are highlighted, including oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), nitrogen reduction reaction (NRR), and carbon dioxide reduction reaction (CRR). Their importance in various electrochemical reactions and present strategies for constructing high‐energy facets are discussed, including alloying, heterostructure formation, selective etching, capping agents, and coupling with substrates. These strategies enable control over crystallographic orientation and surface morphology, fine‐tuning electrocatalytic properties. This study also addresses future directions and challenges, emphasizing the need to better understand fundamental mechanisms. Overall, high‐energy facets offer exciting opportunities for advancing electrocatalysis.

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Authors
Wang, R., & Lee, J.
Affiliations
Nanyang Technological University (SG)
Corresponding author
Lee, Jong‐Min
ORCID
Lee, Jong‐Min
Venue
Small
Publisher
Wiley
Published
2024-05-05
Volume
20
Issue
36
Pages
e2401546-e2401546
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
DOI
10.1002/smll.202401546
OpenAlex
W4396675515
Cited by
32
References
121
Citations by year
2026: 19 · 2025: 12 · 2024: 1
FWCI
0.67
Type
journal article
Language
en
Open access
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations
  • Small (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
Keywords
high-energy facets, facet engineering, electrocatalysts, oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, nitrogen reduction reaction, alloying, heterostructures, selective etching, capping agents, crystal orientation, surface morphology

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