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Cited by 29Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsFuel Cells and Related Materials

Noble Metal Phosphides: Robust Electrocatalysts toward Hydrogen Evolution Reaction

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Guo, Bingrong, Wen, Xinxin, Xu, Li, Ren, Xiaoqian, Niu, Siqi, YangCheng, Ruixue, Ma, Guoxin, Zhang, Junchao +3 more·2023·Small Methods
DOI 10.1002/smtd.202301469
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Abstract

from electrocatalytic hydrogen evolution reaction (HER) has received extensive research interest. Almost all kinds of noble metal phosphides (NMPs) consisting of Pt-group elements (i.e., Ru, Rh, Pd, Os, Ir and Pt) are all highly active and pH-universal electrocatalysts toward HER. In this review, the recent progress of NMP-based HER electrocatalysts is summarized. It is further take typical examples for discussing important impact factors on the HER performance of NMPs, including crystalline phase, morphology, noble metal element and doping. Moreover, the synthesis and HER application of hybrid catalysts consisting of NMPs and other materials such as transition metal phosphides, oxides, sulfides and phosphates, carbon materials and noble metals is also reviewed. Reducing the use of noble metal is the key idea for NMP-based hybrid electrocatalysts, while the expanded functionality and structure-performance relationship are also noticed in this part. At last, the potential opportunities and challenges for this kind of highly active catalyst is discussed.

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  • The limited natural abundance and prohibitive costs of noble metal-based materials severely restrict their widespread commercialization.

    “Although extensive research has shown that noble metal-based materials generally exhibit the highest HER activity, their limited natural abundance and prohibitive costs severely restrict their widespread commercialization [9–13].”

    From Rational synthesis of Au3Cu@Rhx core–shell aerogel electrocatalysts for efficient hydrogen evolution reaction (2026) · cites this paper as [10]

    The Introduction (page not available) identifies the high cost of noble metal phosphides and a performance–cost trade-off for widespread application. It does not state that limited natural abundance is a constraint, so that part of the attributed claim is unsupported by our copy. (LLM, conf=0.84)

    Experimental — accuracy not yet measured

  • Noble metal-based materials generally exhibit the highest HER activity.

    “Although extensive research has shown that noble metal-based materials generally exhibit the highest HER activity, their limited natural abundance and prohibitive costs severely restrict their widespread commercialization [9–13].”

    From Rational synthesis of Au3Cu@Rhx core–shell aerogel electrocatalysts for efficient hydrogen evolution reaction (2026) · cites this paper as [10]

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Authors
Guo, B., Wen, X., Xu, L., Ren, X., Niu, S., YangCheng, R., Ma, G., Zhang, J., Guo, Y., Xu, P., & Li, S.
Affiliations
  • Xi'an Jiaotong University (CN)
  • Novel Energy Materials & Catalysis Research Center Shanwei Innovation Industrial Design & Research Institute Shanwei 516600 P. R. China
  • Dalian Institute of Chemical Physics (CN)
  • Northwestern Polytechnical University (CN)
  • Harbin Institute of Technology (CN)
Corresponding author
  • Niu, Siqi
  • Guo, Ying
  • Xu, Ping
  • Li, Siwei
ORCID
Venue
Small Methods
Publisher
Wiley
Published
2023-12-31
Volume
8
Issue
10
Pages
e2301469-e2301469
ISSN
2366-9608 (ISSN-L)
DOI
10.1002/smtd.202301469
OpenAlex
W4390474166
Cited by
29
References
180
Citations by year
2026: 2 · 2025: 8 · 2024: 19
FWCI
0.44
Type
journal article
Language
en
Open access
Licence
Locations
  • Small Methods (publishedVersion, cc-by-nc-nd)
  • PubMed (publishedVersion)
Funders
National Natural Science Foundation of China (22209178, 22201232, 22209129)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
Keywords
hydrogen evolution reaction, electrocatalysts, platinum group metals, hybrid electrocatalyst, doping, crystalline phase, morphology (materials science), structure-performance relationship, transition metal phosphides, carbon materials, pH universality

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