Green Chemistry: Advanced Electrocatalysts and System Design for Ammonia Oxidation
Open accessAbstract
The hazards associated with handling hydrogen fuels have driven people to consider alternative clean and sustainable fuel types. Ammonia shows significant potential for this task as both a direct fuel and hydrogen carrier due to its unique features of facile transportation and low cost. Regarding this, electrochemical ammonia oxidation reaction (AOR) is the essential process for utilizing ammonia for energy applications, either for hydrogen production via ammonia splitting or energy generation via direct ammonia fuel cells, which is highly commercially promising. On this basis, the development of high‐performance and economic electrocatalysts for AOR is critical. In this review, the kinetics and mechanism of ammonia electrooxidation are first discussed to provide a foundation to understand the current issues associated with this technology, and then a comprehensive presentation on the different types of electrocatalysts for AOR is illustrated. Afterward, an outlook is presented and the possible research directions for AOR electrocatalysis are proposed, which is expected to shed light on the future development of this promising technology.
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Adsorption of reaction by-products blocks active sites and significantly diminishes catalytic performance over time.
“This adsorption blocks active sites, significantly diminishing the catalytic performance over time [21,22].”
From Hydrogen production via ammonia using trimetallic-doped aerogels based on Fe, Ni, Co (2025) · cites this paper as [22]
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- Authors
- Tian, Y., Mao, Z., Wang, L., & Liang, J.
- Affiliations
- Tianjin University (CN)
- Tianjin Normal University (CN)
- Corresponding author
- Liang, Ji
- Venue
- Small Structures
- Publisher
- Wiley
- Published
- 2023-01-26
- Volume
- 4
- Issue
- 6
- ISSN
- 2688-4062 (ISSN-L)
- OpenAlex
- W4318200071
- Cited by
- 112
- References
- 111
- Citations by year
- 2026: 19 · 2025: 45 · 2024: 38 · 2023: 10
- FWCI
- 5.35
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Small Structures (publishedVersion, cc-by)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Funders
- National Natural Science Foundation of China (22179093, 21905202)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Ammonia Synthesis and Nitrogen Reduction
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Keywords
- ammonia oxidation, electrocatalysts, ammonia fuel cells, hydrogen production, hydrogen carrier, reaction kinetics, reaction mechanism, green chemistry, electrochemical energy conversion
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