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The Conversion of Fructose and Glucose in Acidic Media: Formation of Hydroxymethylfurfural

van Dam, H. E., Kieboom, A. P. G., van Bekkum, H.·1986·Starch - Stärke
DOI 10.1002/star.19860380308
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Abstract

The effects of several variables on the reactions of fructose and glucose in acidic media have been studied at moderate reaction conditions. Glucose gives rise to the reversible formation of oligosaccharides (reversion products). Fructose was dehydrated into mixtures of hydroxymethylfurfural, levulinic acid, and humines. In addition, substantial reversible dimerisation of fructose occurred in acidic aqueous solutions. The dimerisation equilibrium, which is shifted by a decrease in the water concentration, lowers the concentration of reactive fructose thereby affecting the selectivity of the dehydration process. p ‐Toluenesulfonic acid proved to be the most effective catalyst for the formation of HMF from fructose. No specific salt effects were found for the hydrochloric acid catalyzed dehydration of fructose.

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Research works printed but not linked: 65

  1. Anet E. F. L., 1964, Adv. Carbohydr. Chem., 19, 203
  2. 10.1016/S0065-2318(08)60383-2 · DOI · Paper page
  3. Pigman W, 1982, The Carbohydrates, 165
  4. 10.1016/S0008-6215(00)80500-5 · DOI
  5. Heyns K., 1970, Ann., 733, 159
  6. 10.1021/jo00919a036 · DOI
  7. 10.1016/S0008-6215(00)81822-4 · DOI
  8. 10.1021/ja00834a031 · doi:10.1021/ja00834a031
  9. 10.1016/0003-9861(77)90228-4 · doi:10.1016/0003-9861(77)90228-4
  10. McKibbins S: Ph. D. Thesis Univ. of Wisconsin1958.
  11. Dworschak E., 1967, Ernährungsforschung, 12, 417
  12. 10.1002/food.19710150107 · doi:10.1002/food.19710150107
  13. 10.1016/S0008-6215(00)84808-9 · DOI
  14. 10.1071/CH9721695 · DOI · Paper page
  15. 10.1021/ja01140a528 · doi:10.1021/ja01140a528
  16. 10.1071/CH9761249 · doi:10.1071/ch9761249
  17. 10.1016/S0008-6215(00)84649-2 · doi:10.1016/s0008-6215(00)84649-2
  18. 10.1021/jo01065a067 · DOI
  19. Martinez Sanchez M. C., 1977, An. Quim., 73, 910
  20. Martinez Sanchez M. C., 1977, An. Quim., 73, 908
  21. Soler A., 1976, An. Quim., 72, 957
  22. 10.3891/acta.chem.scand.08-0436 · doi:10.3891/acta.chem.scand.08-0436
  23. McDonald E. J., 1946, Adv. Carbohydr. Chem., 2, 265
  24. Verstraeten L. M. J., 1967, Adv. Carbohydr. Chem., 22, 258
  25. Soler A., 1975, An. Univ. Murcia, Cienc., 32, 27
  26. Krol B., 1978, Acta. Aliment. Pol., 4, 287
  27. 10.1016/S0008-6215(00)82007-8 · doi:10.1016/s0008-6215(00)82007-8
  28. 10.1016/S0008-6215(00)82791-3 · doi:10.1016/s0008-6215(00)82791-3
  29. Pazur J. H., 1970, The Carbohydrates, 96
  30. Krol B., 1978, Acta. Aliment. Pol., 4, 373
  31. 10.1016/S0008-6215(00)84806-5 · DOI · Paper page
  32. 10.1021/ja01641a051 · doi:10.1021/ja01641a051
  33. Krupenskii V. I., 1978, Khim. Drev., 1, 72
  34. C.A., 88, 170504w
  35. C. A., 47, 615f
  36. C. A., 72, 90257c
  37. C. A., 56, 4732d
  38. Jpn. Pat. 80 13 243 (1980 · doi:10.1038/scientificamerican0880-80
  39. C. A., 93, 26260e
  40. Krupenskii V. I., 1983, Khim. Drev., 5, 90
  41. C. A., 99, 177713e
  42. 10.1002/ardp.19662990726 · doi:10.1002/ardp.19662990726
  43. C. A., 100, 120866s
  44. Krupenskii V. I., 1978, Izv. Vyssh. Uchebn. Zaved., Lesn. Zh., 21, 110
  45. C. A., 90, 39140d
  46. 10.1021/ja01641a049 · doi:10.1021/ja01641a049
  47. 10.1021/jo01049a013 · DOI
  48. U. S. Pat. 2 750 394 (1956); · doi:10.1049/jiee-3.1956.0390
  49. 10.1016/S0008-6215(00)84807-7 · DOI
  50. 10.1002/jctb.5010160703 · DOI
  51. 10.1002/star.19770290507 · DOI
  52. 10.1246/bcsj.53.3705 · DOI
  53. C. A., 94, 156646s
  54. Jpn. Pat. 80 13 243 (1980). · doi:10.1038/scientificamerican0880-80
  55. 10.1002/jctb.503310119 · doi:10.1002/jctb.503310119
  56. Bonner T. G. E. J.BourneandM.Ruskiewicz:J. Chem. Soc.(1960) 787; · DOI
  57. Shur A. A., 1966, Tr. Kiskinev. Polytekh. Inst., 5, 67
  58. C. A., 67, 99923w
  59. 10.1002/jctb.503310165 · DOI
  60. Fr. Pat. 79 22 251 (1979); · doi:10.1093/comjnl/22.1.79
  61. 10.1021/i300004a025 · DOI
  62. 10.1016/0144-4565(83)90003-3 · DOI
  63. 10.1002/star.19770290306 · DOI
  64. 10.1016/0008-6215(83)88406-7 · DOI
  65. 10.1016/S0008-6215(00)85450-6 · DOI

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Metadata

Authors
van Dam, H. E., Kieboom, A. P. G., & van Bekkum, H.
Venue
Starch - Stärke
Publisher
Wiley
Published
1986-01
Volume
38
Issue
3
Pages
95-101
ISSN
  • 0038-9056 (ISSN-L)
  • 1521-379X
DOI
10.1002/star.19860380308
OpenAlex
W2130099673
Cited by
312
References
0
FWCI
2.51
Type
journal article
Language
en
Open access
closed
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor, 7600 d)

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CoChat. (2026). Citation check: The Conversion of Fructose and Glucose in Acidic Media: Formation of Hydroxymethylfurfural. https://app.cochat.ai/papers/10.1002/star.19860380308
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van Dam, H. E., Kieboom, A. P. G., & van Bekkum, H. (1986). The Conversion of Fructose and Glucose in Acidic Media: Formation of Hydroxymethylfurfural. Starch - Stärke. https://doi.org/10.1002/star.19860380308

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