The DOI matches its Crossref record.
Eine mit Tetraederketten aufgefüllte Rutilstruktur: Die Verbindung CaCu4P2≙CaP2(Cu4)
Abstract
CaCu 4 P 2 wurde aus den Elementen dargestellt (geringer Cu‐Überschuß, 850–950°C) und röntgenographisch mit Einkristallmethoden untersucht. Die Verbindung kristallisiert tetragonal (P4 2/mnm, a = 729, 0(2) pm, c = 383, 1(1) pm) in einer von Ca‐ und P‐Atomen aufgebauten Rutilstruktur, bei welcher Cu‐Atome in Form kantenverknüpfter Tetraederketten die noch freien Plätze besetzen.
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Cu8P4SrTm was identified as having the same structure as CaCu4P2, with the lattice parameters switched and the predicted compound pseudo-tetragonal.
“For example, Cu8P4SrTm was identified as having the same structure as CaCu4P2,22 noting that the lattice parameters were switched between the two entries and that the predicted compound was pseudo-tetragonal.”
From Artificial Intelligence Driving Materials Discovery? Perspective on the Article: Scaling Deep Learning for Materials Discovery (2024) · cites this paper as [22]
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Research works printed but not linked: 2
- Mewis A., 1980, Z. Naturforsch., 35, 942, 10.1515/znb-1980-0802 · DOI
- Pauling L., 1968, Die Natur der chemischen Bindung, 479
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Cheetham, A. K., & Seshadri, R. (2024) · Chemistry of Materials · doi:10.1021/acs.chemmater.4c00643 · Cited by 191
Metadata
- Authors
- Mewis, A.
- Affiliations
- University of Cologne (DE)
- Corresponding author
- Mewis, A.
- Venue
- Zeitschrift für anorganische und allgemeine Chemie
- Publisher
- Wiley
- Published
- 1987-02
- Volume
- 545
- Issue
- 2
- Pages
- 43-46
- ISSN
- 0044-2313 (ISSN-L)
- 1521-3749
- OpenAlex
- W2049939000
- Cited by
- 13
- References
- 0
- Citations by year
- 2024: 1 · 2023: 1 · 2013: 1 · 2012: 1
- FWCI
- 1.09
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Zeitschrift für anorganische und allgemeine Chemie (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Crystal Structures and Properties
- Physical Sciences › Chemistry › Inorganic Chemistry › Inorganic Chemistry and Materials
- Physical Sciences › Chemistry › Inorganic Chemistry › Crystal structures of chemical compounds
- Keywords
- tetrahedral chains, tetragonal crystal structure, calcium phosphide, copper phosphide, crystal structure
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