The DOI matches its Crossref record; 25 of the 25 references it cites were found in a registry or an index.
Crystal Structure of Iron(II) Acetate
Abstract
In this paper the X‐ray structure and magnetic properties of iron(II) acetate – starting material for the synthesis of a wide range of iron complexes – are presented. The compound crystallises in the space group Pbcn and was identified as 2D coordination polymer consisting of iron atoms and acetate moieties with all the iron atoms hexacoordinate and different coordination modes for the acetate moieties. Additional hydrogen bond contacts lead to a porous coordination polymer with 1D channels in the size of mesopores. Temperature dependent magnetic measurements confirm that the complex is a high‐spin compound in the entire temperature range investigated with a room temperature magnetic moment of 5.4 μ B . Field‐dependent magnetisation measurements reveal a slightly sigmoidal curve progression typical for metamagnetism.
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“Undissolved iron(ii) acetate is a polymeric network that contains various acetate binding modes and significant amounts of oxide and hydroxide functions.78”
From Iron( ii ) carboxylates and simple carboxamides: an inexpensive and modular catalyst system for the synthesis of PLLA and PLLA-PCL block copolymers (2023) · cites this paper as [78]
Citations
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Cited by
An intrinsic growth instability in isotropic materials leads to quasi-two-dimensional nanoplatelets
Riedinger, A., Ott, F. D., Mule, A., Mazzotti, S., Knüsel, P. N., Kress, S. J. P., Prins, F., Erwin, S. C., & Norris, D. J. (2017) · Nature Materials · doi:10.1038/nmat4889 · Cited by 264
Lochenie, C., Schötz, K., Panzer, F., Kurz, H., Maier, B., Puchtler, F., Agarwal, S., Köhler, A., & Weber, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10571 · Cited by 229
Self-citationInfluence of Hydrogen Bonding on the Hysteresis Width in Iron(II) Spin‐Crossover Complexes
Weber, B., Bauer, W., Pfaffeneder, T., Dîrtu, M. M., Naik, A. D., Rotaru, A., & Garcia, Y. (2011) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201100394 · Cited by 121
Self-citationLarge Thermal Hysteresis for Iron(II) Spin Crossover Complexes with N-(Pyrid-4-yl)isonicotinamide
Lochenie, C., Bauer, W., Railliet, A. P., Schlamp, S., Garcia, Y., & Weber, B. (2014) · Inorganic Chemistry · doi:10.1021/ic501624b · Cited by 95
Self-citationGordon, J. B., Vilbert, A., DiMucci, I. M., MacMillan, S. N., Lancaster, K. M., Moënne‐Loccoz, P., & Goldberg, D. P. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b05274 · Cited by 66
Metadata
- Authors
- Weber, B., Betz, R., Bauer, W., & Schlamp, S.
- Affiliations
- Center for Integrated Protein Science Munich (DE)
- University of Bayreuth (DE)
- Corresponding author
- Weber, Birgit
- Venue
- Zeitschrift für anorganische und allgemeine Chemie
- Publisher
- Wiley
- Published
- 2010-12
- Volume
- 637
- Issue
- 1
- Pages
- 102-107
- ISSN
- 0044-2313 (ISSN-L)
- 1521-3749
- OpenAlex
- W2156965083
- Semantic Scholar
- e998cda859f919d5d20a390bf8ee757a9e4e27fd
- Cited by
- 64
- References
- 23
- Citations by year
- 2026: 4 · 2025: 4 · 2024: 1 · 2023: 3 · 2022: 4 · 2021: 6 · 2020: 7 · 2019: 4 · 2018: 7 · 2017: 5 · 2016: 1 · 2015: 1 · 2014: 5 · 2013: 4 · 2012: 1
- FWCI
- 2.35
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Zeitschrift für anorganische und allgemeine Chemie (publishedVersion)
- Nelson Mandela University Research Repository (submittedVersion)
- Funders
- Deutsche Forschungsgemeinschaft
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Magnetism in coordination complexes
- Physical Sciences › Chemistry › Inorganic Chemistry › Crystal structures of chemical compounds
- Keywords
- iron(II) acetate, crystal structure, coordination polymers, hydrogen bonding, metal-organic frameworks, mesopores, high-spin states, magnetic properties, metamagnetism
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
