Introduction to the Zeolite Structure-Directing Phenomenon by Organic Species: General Aspects
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The lower charge density of OSDAs compared with alkaline and alkaline-earth cations allows for less charged frameworks, thus facilitating the obtention of final materials with a higher Si/Al ratio.
“The lower charge density of the OSDAs in comparison with the alkaline and alkaline-earth cations allows for less charged frameworks, thus facilitating the obtention of final materials with a higher Si/Al ratio.47,55”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [47]
The most remarkable type of SDAs and the ones that meant a breakthrough in zeolite science are organic SDAs (OSDAs), which are in most cases amines and alkylammonium cations.
“Nonetheless, the most remarkable type of SDAs and the ones that meant a breakthrough in zeolite science are organic SDAs (OSDAs), which are in most cases amines and alkylammonium cations.45−48”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [47]
The way in which OSDAs favor the crystallization of a specific structure is not yet fully understood, despite the large research effort put into it.
“The way in which these OSDAs favor the crystallization of a specific structure is not yet fully understood, despite the large research effort put into it.46,47,95,96”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [47]
Cites
On the controllable soft-templating approach to mesoporous silicates
Wan, Y., & Zhao (2007) · Chemical Reviews · doi:10.1021/cr068020s · Cited by 2,371 · see citing works
Synthesis of all-silica and high-silica molecular sieves in fluoride media
Camblor, M. A., Villaescusa, L. A., & Díaz-Cabañas, M. J. (1999) · Topics in Catalysis · doi:10.1023/a:1019154304344 · Cited by 383 · see citing works
Self-citation“Ab initio” synthesis of zeolites for preestablished catalytic reactions
Gallego, E. M., Portilla, M. T., Paris, C., León-Escamilla, A., Boronat, M., Moliner, M., & Corma, A. (2017) · Science · doi:10.1126/science.aal0121 · Cited by 253 · see citing works
Studies on the Role of Fluoride Ion vs Reaction Concentration in Zeolite Synthesis
Zones, S. I., Darton, R. J., Morris, R., & Hwang, S.-J. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0402434 · Cited by 115 · see citing works
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Zeolites in Adsorption Processes: State of the Art and Future Prospects
Pérez-Botella, E., Valencia, S., & Rey, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00140 · Cited by 1,126 · see citing works
- Authors
- Gómez-Hortigüela, L., & Camblor, M. Á.
- Venue
- Structure and Bonding
- Publisher
- Springer International Publishing
- Published
- 2017
- Pages
- 1-41
- ISSN
- 0081-5993 (ISSN-L)
- 1616-8550
- OpenAlex
- W2763446409
- Cited by
- 35
- References
- 4
- Citations by year
- 2026: 2 · 2025: 5 · 2024: 5 · 2023: 5 · 2022: 5 · 2021: 6 · 2020: 3 · 2019: 3 · 2018: 1
- FWCI
- 6.54
- Type
- book chapter
- Language
- en
- Open access
- closed
- Locations
- Structure and bonding (publishedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Keywords
- zeolite synthesis, structure-directing agent, organic cations, imidazolium cations, host-guest chemistry, crystallization, zeolite framework types, hydrophobicity, hydrothermal stability, heteroatom incorporation, fluoride, molecular size and shape
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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