Mechanisms of Chemiluminescence and Bioluminescence
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Electron donors such as transition metal ions, amines, glutathione, vitamin C, vitamin E, NADH, and FADH2 split a dioxetane's O-O bond without C-C cleavage, yielding harmless diols.
“Electron donors such as transition metal ions, amines, glutathione, vitamin C, vitamin E, NADH, and FADH2 split the O–O bond of a dioxetane in a way that is not followed by the C–C cleavage and so yields harmless diols (276, 287, 65, 277, 278, 288).”
From Chemiexcitation: Mammalian Photochemistry in the Dark<sup>†</sup> (2023) · cites this paper as [277]
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References 3 · Cited by 1
- Authors
- Lee, J., Hercules, D. M., & Cormier, M. J.
- Affiliations
- University of Georgia (US)
- Venue
- Chemiluminescence and Bioluminescence
- Publisher
- Springer US
- Published
- 1973
- Pages
- 1-6
- OpenAlex
- W2168236149
- Cited by
- 1
- References
- 3
- FWCI
- 0.00
- Type
- book chapter
- Language
- en
- Open access
- closed
- Locations
- Springer eBooks (publishedVersion)
- Topics
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › bioluminescence and chemiluminescence research
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Advanced Combustion Engine Technologies
- Keywords
- chemiluminescence, bioluminescence, cold light, fireflies, light emission mechanism, gas-phase kinetics, chemical reactions
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
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