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Investigation of the structure of solution grown crystals of lactide copolymers by means of chemical reactions
Abstract
The relationship between crystallisation and melting behaviour of copolymers and their morphology has been the subject of intensive discussion. One of the main points of interest is the distribution of the noncrystallizable units within the partially crystalline systems. For the explanation of physical properties of copolymers very often equilibrium theories (1, 2) are applied which start from the basic assumption that the noncrystallizable units of the polymer chains are rejected from the crystalline regions. On the other hand, the results of some structure studies by means of small angle X-ray scattering revealed strong evidence, that for example in branched polyethylene the comonomer units are partially incorporated in the crystal (3, 4).
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Cited by
A Literature Review of Poly(Lactic Acid)
Garlotta, D. (2001) · Journal of Polymers and the Environment · doi:10.1023/a:1020200822435 · Cited by 3,707
Poly(lactic acid) crystallization
Saeidlou, S., Huneault, M. A., Li, H., & Park, C. B. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.07.005 · Cited by 1,606
Properties of lactic acid based polymers and their correlation with composition
Södergård, A., & Stolt, M. (2002) · Progress in Polymer Science · doi:10.1016/s0079-6700(02)00012-6 · Cited by 1,461
Poly(lactic acid) fiber: An overview
Gupta, B., Revagade, N., & Hilborn, J. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.01.005 · Cited by 1,360
Synthetic nano-scale fibrous extracellular matrix
Ma, P. X., & Zhang, R. (1999) · Journal of Biomedical Materials Research · doi:10.1002/(sici)1097-4636(199907)46:1<60::aid-jbm7>3.0.co;2-h · Cited by 1,049
Metadata
- Authors
- Fischer, E. W., Sterzel, H. J., & Wegner, G.
- Venue
- Aktuelle Probleme der Polymer-Physik
- Publisher
- Steinkopff
- Published
- 1973
- Pages
- 980-990
- ISSN
- 0340-210X (ISSN-L)
- OpenAlex
- W2049224077
- Cited by
- 679
- References
- 0
- FWCI
- 0.00
- Type
- book chapter
- Language
- en
- Open access
- closed
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- Fischer, E. W., Sterzel, H. J., & Wegner, G. (1973). Investigation of the structure of solution grown crystals of lactide copolymers by means of chemical reactions. Aktuelle Probleme der Polymer-Physik. https://doi.org/10.1007/978-3-642-47050-9_24
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