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[Zn(bim)2] · (H2O)1.67: A metal-organic open-framework with sodalite topology
Abstract
The new coordination polymer formulated as [Zn(bim) 2 ]·(H 2 O) 1.67 (Hbim = benzimidazole, bim = benzimi-dazolate) has been synthesized and shown by single-crystal structural analysis to be a three-dimensional network with the 4 2 6 4 sodalite topology, constructed by tetrahedral building blocks, [Zn(bim) 4 ] 2− . Each sodalite cage defined by the 24 zinc atoms at the apexes centers hosts 10 water molecules (ca. 18% occupancy).
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Metadata
- Authors
- Huang, X., Zhang, J., & Chen, X.
- Venue
- Chinese Science Bulletin
- Published
- 2003-08
- Volume
- 48
- Issue
- 15
- Pages
- 1531-1534
- ISSN
- 1001-6538 (ISSN-L)
- 1861-9541
- OpenAlex
- W1981212205
- Cited by
- 169
- References
- 0
- FWCI
- 1.61
- Type
- journal article
- Language
- en
- Open access
- closed
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