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Modeling of sorption kinetics: the pseudo-second order equation and the sorbate intraparticle diffusivity

Open access
Plazinski, Wojciech, Dziuba, Jakub, Rudzinski, Wladyslaw·2013·Adsorption

Abstract

The applicability of the pseudo-second order equation (PSOE) has been explained on the ground of the model assuming that the overall sorption rate is limited by the rate of sorbate diffusion in the pores of sorbent (intraparticle diffusion model). Mathematical expressions have been proposed in order to describe the dependence of the pseudo-second order constant on such parameters as the initial sorbate concentration, the progress of the sorption process and the solid/solution ratio. Further, it has been shown that equilibrium sorption capacities estimated by using PSOE may be much lower than the actual ones: it depends mainly on how the sorption system is close to equilibrium. The values of parameters applied in calculations were taken from the literature and correspond to the biosorption systems designed to remove the heavy metals from the aqueous solution.

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Metadata

Authors
Plazinski, W., Dziuba, J., & Rudzinski, W.
Venue
Adsorption
Published
2013-03-06
Volume
19
Issue
5
Pages
1055-1064
ISSN
  • 0929-5607 (ISSN-L)
  • 1572-8757
OpenAlex
W2072173153
Cited by
317
References
23
FWCI
9.04
Type
journal article
Language
en
Open access
hybrid

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Plazinski, W., Dziuba, J., & Rudzinski, W. (2013). Modeling of sorption kinetics: the pseudo-second order equation and the sorbate intraparticle diffusivity. Adsorption. https://doi.org/10.1007/s10450-013-9529-0

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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