The DOI matches its Crossref record; 112 of the 112 references it cites were found in a registry or an index.
Review of the anatase to rutile phase transformation
Open accessAbstract
Titanium dioxide, TiO2, is an important photocatalytic material that exists as two main polymorphs, anatase and rutile. The presence of either or both of these phases impacts on the photocatalytic performance of the material. The present work reviews the anatase to rutile phase transformation. The synthesis and properties of anatase and rutile are examined, followed by a discussion of the thermodynamics of the phase transformation and the factors affecting its observation. A comprehensive analysis of the reported effects of dopants on the anatase to rutile phase transformation and the mechanisms by which these effects are brought about is presented in this review, yielding a plot of the cationic radius versus the valence characterised by a distinct boundary between inhibitors and promoters of the phase transformation. Further, the likely effects of dopant elements, including those for which experimental data are unavailable, on the phase transformation are deduced and presented on the basis of this analysis.
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Cites
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Recent advances in photocatalysis for environmental applications
Byrne, C., Subramanian, G., & Pillai, S. C. (2018) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2017.07.080 · Cited by 820
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Nanoscale TiO2 films and their application in remediation of organic pollutants
Varshney, G., Kanel, S. R., Kempisty, D. M., Varshney, V., Agrawal, A., Sahle-Demessie, E., Varma, R. S., & Nadagouda, M. N. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.06.011 · Cited by 160
Tian, X., Wang, Y., Zeng, Z., Dai, L., Xu, J., Cobb, K., Ke, L., Zou, R., Liu, Y., & Ruan, R. (2022) · Green Chemistry · doi:10.1039/d1gc04537g · Cited by 128
Metadata
- Authors
- Hanaor, D. A. H., & Sorrell, C. C.
- Venue
- Journal of Materials Science
- Published
- 2010-12-08
- Volume
- 46
- Issue
- 4
- Pages
- 855-874
- ISSN
- 0022-2461 (ISSN-L)
- 1573-4803
- OpenAlex
- W2050041941
- Cited by
- 3,394
- References
- 112
- FWCI
- 22.53
- Type
- journal article
- Language
- en
- Open access
- hybrid
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