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Elimination performance of methylene blue, methyl violet, and Nile blue from aqueous media using AC/CoFe2O4 as a recyclable magnetic composite
Abstract
The present paper describes the sono-assisted adsorption (sono-adsorption) of methylene blue (MB), methyl violet (MV), and Nile blue (NB) from aqueous solution by AC/CoFe 2 O 4 magnetic composite. FT-IR, TGA-DTG, VSM, XRD, TEM, SEM, EDX, Map, and Raman analysis were used to characterize the magnetic composite. The magnetization saturation value of AC/CoFe 2 O 4 magnetic composite was determined to be 53.06 emu/g. Dye sono-adsorption efficiency was increased by increasing adsorbent dose, pH value, and contact time, but not dye concentration. Pseudo-first-order, pseudo-second-order, and intra-particle diffusion models were used to study the kinetic behavior of the cationic dye sono-adsorption. The sono-adsorption kinetics was reasonably followed by pseudo-second-order model (R 2 > 0.998). The results showed that the Freundlich model (R 2 > 0.976) was more able to describe the sono-adsorption equilibrium behavior than Langmuir, D-R, and Scatchard models. The maximum sono-adsorption capacity of NB, MV, and MB was determined as 86.24, 83.90, and 87.48 mg/g, respectively. Based on the parameters derived from isotherm modeling (R L, n, and E), the sono-adsorption process of cationic dyes is desirable and physical. An increase in NaCl concentration reduced the sono-adsorption efficiency for all dyes. Also, the adsorption-desorption of AC/CoFe 2 O 4 magnetic was studied up to 10 stages, and it was confirmed that the sono-adsorption efficiency is acceptable up to the eight stage. AC/CoFe 2 O 4 magnetic composite is, therefore, an affordable and recyclable adsorbent to remove the molecule of NB, MV, and MB dyes from aqueous media.
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Activated carbon is widely used to remove dyes from wastewater because of its convenience, ease of operation, simplicity of design, and reusability.
“Activated carbon is widely used to remove dyes from wastewater because of its convenience, ease of operation, simplicity of design, and reusability1–3,35–37.”
From The removal of anionic and cationic dyes from an aqueous solution using biomass-based activated carbon (2021) · cites this paper as [36]
Some commercial activated carbon remains an expensive material.
“However, despite its extensive use in wastewater treatment, some commercial activated carbon remains an expensive material35–37.”
From The removal of anionic and cationic dyes from an aqueous solution using biomass-based activated carbon (2021) · cites this paper as [36]
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References 78 · Cited by 113
Metadata
- Authors
- Foroutan, R., Mohammadi, R., & Ramavandi, B.
- Affiliations
- University of Tabriz (IR)
- Bushehr University of Medical Sciences (IR)
- Corresponding author
- Ramavandi, Bahman
- Venue
- Environmental Science and Pollution Research
- Published
- 2019-05-10
- Volume
- 26
- Issue
- 19
- Pages
- 19523-19539
- ISSN
- 0944-1344 (ISSN-L)
- 1614-7499
- OpenAlex
- W2944037775
- Cited by
- 113
- References
- 78
- Citations by year
- 2026: 12 · 2025: 12 · 2024: 9 · 2023: 22 · 2022: 14 · 2021: 18 · 2020: 25 · 2019: 1
- FWCI
- 5.25
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Environmental Science and Pollution Research (publishedVersion)
- PubMed (publishedVersion)
- Funders
- University of Tabriz (Grant No. UTab. 96122)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Water Science and Technology › Coagulation and Flocculation Studies
- Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
- Keywords
- methylene blue, methyl violet, Nile blue, cationic dye removal, magnetic composite adsorbent, cobalt ferrite, activated carbon, adsorption kinetics, adsorption isotherms, adsorbent reusability, dye wastewater treatment
- MeSH terms
- Adsorption, Charcoal, Cobalt, Diffusion, Coloring Agents, Ferric Compounds, Gentian Violet, Hydrogen-Ion Concentration, Kinetics, Methylene Blue, Oxazines, Water Pollutants, Chemical, Water Purification, Magnetite Nanoparticles
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