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Raman spectroscopy of graphene on different substrates and influence of defects
Open accessAbstract
We show the evolution of Raman spectra with a number of graphene layers on different substrates, SiO2/Si and conducting indium tin oxide (ITO) plate. The G mode peak position and the intensity ratio of G and 2D bands depend on the preparation of sample for the same number of graphene layers. The 2D Raman band has characteristic line shapes in single and bilayer graphene, capturing the differences in their electronic structure. The defects have a significant influence on the G band peak position for the single layer graphene: the frequency shows a blue shift up to 12 cm−1 depending on the intensity of the D Raman band, which is a marker of the defect density. Most surprisingly, Raman spectra of graphene on the conducting ITO plates show a lowering of the G mode frequency by ∼ 6 cm−1 and the 2D band frequency by ∼ 20 cm−1. This red-shift of the G and 2D bands is observed for the first time in single layer graphene.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Two-dimensional gas of massless Dirac fermions in graphene
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Katsnelson, M. I., Grigorieva, I. V., Dubonos, S. V., & Firsov, A. A. (2005) · Nature · doi:10.1038/nature04233 · Cited by 21,611
Experimental observation of the quantum Hall effect and Berry's phase in graphene
Zhang, Y., Tan, Y.-W., Stormer, H. L., & Kim, P. (2005) · Nature · doi:10.1038/nature04235 · Cited by 13,435
Two-dimensional atomic crystals
Novoselov, K. S., Jiang, D., Schedin, F., Booth, T. J., Khotkevich, V. V., Morozov, S. V., & Geim, A. K. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0502848102 · Cited by 11,788
Electronic properties of disordered two-dimensional carbon
Peres, N. M. R., Guinea, F., & Castro Neto, A. H. (2006) · Physical Review B · doi:10.1103/physrevb.73.125411 · Cited by 1,445
Cited by
The electronic properties of graphene
Castro Neto, A. H., Guinea, F., Peres, N. M. R., Novoselov, K. S., & Geim, A. K. (2009) · Reviews of Modern Physics · doi:10.1103/revmodphys.81.109 · Cited by 24,803
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Scalable production of graphene sheets by mechanical delamination
Knieke, C., Berger, A., Voigt, M., Taylor, R. N. K., Röhrl, J., & Peukert, W. (2010) · Carbon · doi:10.1016/j.carbon.2010.05.003 · Cited by 243
Understanding Pt Nanoparticle Anchoring on Graphene Supports through Surface Functionalization
Xin, L., Yang, F., Rasouli, S., Qiu, Y., Li, Z.-F., Uzunoglu, A., Sun, C.-J., Liu, Y., Ferreira, P., Li, W., et al. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02722 · Cited by 209
Zhou, H., Zhang, J., Amiinu, I. S., Zhang, C., Liu, X., Tu, W., Pan, M., & Mu, S. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp00174b · Cited by 128
Metadata
- Authors
- Das, A., Chakraborty, B., & Sood, A. K.
- Venue
- Bulletin of Materials Science
- Published
- 2008-06
- Volume
- 31
- Issue
- 3
- Pages
- 579-584
- ISSN
- 0250-4707 (ISSN-L)
- 0973-7669
- OpenAlex
- W2145153471
- Cited by
- 649
- References
- 5
- FWCI
- 5.39
- Type
- journal article
- Language
- en
- Open access
- green
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