The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
Porous CuO nanowires as the anode of rechargeable Na-ion batteries
Abstract
We report the preparation of porous CuO nanowires that are composed of nanoparticles (∼50 nm) via a simple decomposition of a Cu(OH)2 precursor and their application as the anode materials of rechargeable Na-ion batteries. The as-prepared porous CuO nanowires exhibit a Brunauer-Emmett-Teller (BET) surface area of 13.05 m2·g−1, which is six times larger than that of bulk CuO (2.16 m2·g−1). The anode of porous CuO nanowires showed discharge capacities of 640 mA·h·g−1 in the first cycle and 303 mA·h·g−1 after 50 cycles at 50 mA·g−1. The high capacity is attributed to porous nanostructure which facilitates fast Na-intercalation kinetics. The mechanism of electrochemical Na-storage based on conversion reactions has been studied through cyclic voltammetry, X-ray diffraction (XRD), Raman spectroscopy, and high resolution transmission electron microscopy (HRTEM). It is demonstrated that in the discharge process, Na+ ions first insert into CuO to form a Cu 1− II Cu I O1−x/2 solid and a Na2O matrix then Cu 1− II Cu I O1−x/2 reacts with Na+ to produce Cu2O, and finally Cu2O decompose into Cu nanoparticles enclosed in a Na2O matrix. During the charge process, Cu nanoparticles are first oxidized to generate Cu2O and then converted back to CuO. This result contributes to the design and mechanistic analysis of high-performance anodes for rechargeable Na-ion batteries.
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Cites
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
Palomares, V., Serras, P., Villaluenga, I., Hueso, K. B., Carretero-González, J., & Rojo, T. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02781j · Cited by 3,564
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
Yabuuchi, N., Kajiyama, M., Iwatate, J., Nishikawa, H., Hitomi, S., Okuyama, R., Usui, R., Yamada, Y., & Komaba, S. (2012) · Nature Materials · doi:10.1038/nmat3309 · Cited by 2,270
Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications
Cao, Y., Xiao, L., Sushko, M. L., Wang, W., Schwenzer, B., Xiao, J., Nie, Z., Saraf, L. V., Yang, Z., & Liu, J. (2012) · Nano Letters · doi:10.1021/nl3016957 · Cited by 1,929
Electrochemical investigation of the P2–NaxCoO2 phase diagram
Berthelot, R., Carlier, D., & Delmas, C. (2011) · Nature Materials · doi:10.1038/nmat2920 · Cited by 1,232
Nearly Monodisperse Cu2O and CuO Nanospheres: Preparation and Applications for Sensitive Gas Sensors
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Na2Ti3O7: Lowest Voltage Ever Reported Oxide Insertion Electrode for Sodium Ion Batteries
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A rechargeable room-temperature sodium superoxide (NaO2) battery
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Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life
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Cited by
Nanowires for Electrochemical Energy Storage
Zhou, G., Xu, L., Hu, G., Mai, L., & Cui, Y. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00326 · Cited by 439
Na 3 V 2 (PO 4 ) 3 @C core–shell nanocomposites for rechargeable sodium-ion batteries
Duan, W., Zhu, Z., Li, H., Hu, Z., Zhang, K., Cheng, F., & Chen, J. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta00106k · Cited by 411
Self-citation
Metadata
- Authors
- Wang, L., Zhang, K., Hu, Z., Duan, W., Cheng, F., & Chen, J.
- Venue
- Nano Research
- Publisher
- Tsinghua University Press
- Published
- 2013-12-12
- Volume
- 7
- Issue
- 2
- Pages
- 199-208
- ISSN
- 1998-0000 (ISSN-L)
- 1998-0124
- OpenAlex
- W2001233466
- Cited by
- 272
- References
- 26
- FWCI
- 15.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, L., Zhang, K., Hu, Z., Duan, W., Cheng, F., & Chen, J. (2014). Porous CuO nanowires as the anode of rechargeable Na-ion batteries. Nano Research. https://doi.org/10.1007/s12274-013-0387-6
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