The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Phosphorus oxoanion-intercalated layered double hydroxides for high-performance oxygen evolution
Abstract
Rational design and controlled fabrication of efficient and cost-effective electrodes for the oxygen evolution reaction (OER) are critical for addressing the unprecedented energy crisis. Nickel–iron layered double hydroxides (NiFe-LDHs) with specific interlayer anions (i.e. phosphate, phosphite, and hypophosphite) were fabricated by a co-precipitation method and investigated as oxygen evolution electrocatalysts. Intercalation of the phosphorus oxoanion enhanced the OER activity in an alkaline solution; the optimal performance (i.e., a low onset potential of 215 mV, a small Tafel slope of 37.7 mV/dec, and stable electrochemical behavior) was achieved with the hypophosphite-intercalated NiFe-LDH catalyst, demonstrating dramatic enhancement over the traditional carbonate-intercalated NiFe-LDH in terms of activity and durability. This enhanced performance is attributed to the interaction between the intercalated phosphorous oxoanions and the edge-sharing MO 6 (M = Ni, Fe) layers, which modifies the surface electronic structure of the Ni sites. This concept should be inspiring for the design of more effective LDH-based oxygen evolution electrocatalysts.
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Cites
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Bao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502226 · Cited by 1,428
Self-citationHunter, B. M., Blakemore, J. D., Deimund, M., Gray, H. B., Winkler, J. R., & Müller, A. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja506087h · Cited by 321
Cited by
Fe-Based Electrocatalysts for Oxygen Evolution Reaction: Progress and Perspectives
Feng, C., Faheem, M. B., Fu, J., Xiao, Y., Li, C., & Li, Y. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05445 · Cited by 587
Self-citationFu, S., Song, J., Zhu, C., Xu, G.-L., Amine, K., Sun, C., Li, X., Engelhard, M. H., Du, D., & Lin, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2017.12.010 · Cited by 150
Shi, Y., Zhou, S., Liu, J., Zhang, X., Yin, J., Zhan, T., Yang, Y., Li, G., Lai, J., & Wang, L. (2024) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.123326 · Cited by 103
High performance transition metal-based electrocatalysts for green hydrogen production
Kwon, H. R., Park, H., Jun, S. E., Choi, S., & Jang, H. W. (2022) · Chemical Communications · doi:10.1039/d2cc02423c · Cited by 53
Metadata
- Authors
- Luo, M., Cai, Z., Wang, C., Bi, Y., Qian, L., Hao, Y., Li, L., Kuang, Y., Li, Y., Lei, X., Huo, Z., Liu, W., Wang, H., Sun, X., & Duan, X.
- Venue
- Nano Research
- Publisher
- Tsinghua University Press
- Published
- 2017-02-22
- Volume
- 10
- Issue
- 5
- Pages
- 1732-1739
- ISSN
- 1998-0000 (ISSN-L)
- 1998-0124
- OpenAlex
- W2589230098
- Cited by
- 204
- References
- 4
- FWCI
- 4.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Luo, M., Cai, Z., Wang, C., Bi, Y., Qian, L., Hao, Y., Li, L., Kuang, Y., Li, Y., Lei, X., Huo, Z., Liu, W., Wang, H., Sun, X., & Duan, X. (2017). Phosphorus oxoanion-intercalated layered double hydroxides for high-performance oxygen evolution. Nano Research. https://doi.org/10.1007/s12274-017-1437-2
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