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The Surface Coating of Commercial LiFePO4 by Utilizing ZIF-8 for High Electrochemical Performance Lithium Ion Battery

Open access
Xu, XiaoLong, Qi, CongYu, Hao, ZhenDong, Wang, Hao, Jiu, JinTing, Liu, JingBing, Yan, Hui, Suganuma, Katsuaki·2018·Nano-Micro Letters

Abstract

The requirement of energy-storage equipment needs to develop the lithium ion battery (LIB) with high electrochemical performance. The surface modification of commercial LiFePO4 (LFP) by utilizing zeolitic imidazolate frameworks-8 (ZIF-8) offers new possibilities for commercial LFP with high electrochemical performances. In this work, the carbonized ZIF-8 (CZIF-8) was coated on the surface of LFP particles by the in situ growth and carbonization of ZIF-8. Transmission electron microscopy indicates that there is an approximate 10 nm coating layer with metal zinc and graphite-like carbon on the surface of LFP/CZIF-8 sample. The N2 adsorption and desorption isotherm suggests that the coating layer has uniform and simple connecting mesopores. As cathode material, LFP/CZIF-8 cathode-active material delivers a discharge specific capacity of 159.3 mAh g−1 at 0.1C and a discharge specific energy of 141.7 mWh g−1 after 200 cycles at 5.0C (the retention rate is approximate 99%). These results are attributed to the synergy improvement of the conductivity, the lithium ion diffusion coefficient, and the degree of freedom for volume change of LFP/CZIF-8 cathode. This work will contribute to the improvement of the cathode materials of commercial LIB.

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Metadata

Authors
Xu, X., Qi, C., Hao, Z., Wang, H., Jiu, J., Liu, J., Yan, H., & Suganuma, K.
Venue
Nano-Micro Letters
Published
2017-09-25
Volume
10
Issue
1
Pages
1-1
ISSN
  • 2150-5551 (ISSN-L)
  • 2311-6706
OpenAlex
W2757614846
Cited by
258
References
19
FWCI
6.49
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: The Surface Coating of Commercial LiFePO4 by Utilizing ZIF-8 for High Electrochemical Performance Lithium Ion Battery. https://app.cochat.ai/papers/10.1007/s40820-017-0154-4
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Xu, X., Qi, C., Hao, Z., Wang, H., Jiu, J., Liu, J., Yan, H., & Suganuma, K. (2018). The Surface Coating of Commercial LiFePO4 by Utilizing ZIF-8 for High Electrochemical Performance Lithium Ion Battery. Nano-Micro Letters. https://doi.org/10.1007/s40820-017-0154-4

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