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The Surface Coating of Commercial LiFePO4 by Utilizing ZIF-8 for High Electrochemical Performance Lithium Ion Battery
Open accessAbstract
The requirement of energy-storage equipment needs to develop the lithium ion battery (LIB) with high electrochemical performance. The surface modification of commercial LiFePO4 (LFP) by utilizing zeolitic imidazolate frameworks-8 (ZIF-8) offers new possibilities for commercial LFP with high electrochemical performances. In this work, the carbonized ZIF-8 (CZIF-8) was coated on the surface of LFP particles by the in situ growth and carbonization of ZIF-8. Transmission electron microscopy indicates that there is an approximate 10 nm coating layer with metal zinc and graphite-like carbon on the surface of LFP/CZIF-8 sample. The N2 adsorption and desorption isotherm suggests that the coating layer has uniform and simple connecting mesopores. As cathode material, LFP/CZIF-8 cathode-active material delivers a discharge specific capacity of 159.3 mAh g−1 at 0.1C and a discharge specific energy of 141.7 mWh g−1 after 200 cycles at 5.0C (the retention rate is approximate 99%). These results are attributed to the synergy improvement of the conductivity, the lithium ion diffusion coefficient, and the degree of freedom for volume change of LFP/CZIF-8 cathode. This work will contribute to the improvement of the cathode materials of commercial LIB.
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Where do batteries end and supercapacitors begin?
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The effect of carbon coating thickness on the capacity of LiFePO4/C composite cathodes
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Cited by
Dong, W., Xie, M., Zhao, S., Qin, Q., & Huang, F. (2023) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2022.100713 · Cited by 319
Metadata
- Authors
- Xu, X., Qi, C., Hao, Z., Wang, H., Jiu, J., Liu, J., Yan, H., & Suganuma, K.
- Venue
- Nano-Micro Letters
- Published
- 2017-09-25
- Volume
- 10
- Issue
- 1
- Pages
- 1-1
- ISSN
- 2150-5551 (ISSN-L)
- 2311-6706
- OpenAlex
- W2757614846
- Cited by
- 258
- References
- 19
- FWCI
- 6.49
- Type
- journal article
- Language
- en
- Open access
- gold
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- Xu, X., Qi, C., Hao, Z., Wang, H., Jiu, J., Liu, J., Yan, H., & Suganuma, K. (2018). The Surface Coating of Commercial LiFePO4 by Utilizing ZIF-8 for High Electrochemical Performance Lithium Ion Battery. Nano-Micro Letters. https://doi.org/10.1007/s40820-017-0154-4
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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