Spontaneous formation of optically active substances

On spontaneous asymmetric synthesis

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New Procedures for Resolution of Racemic Substances

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Untersuchung Monomolekularer Filme mit Hilfe von Elektronenstrahlen

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Trennung von optischen Antipoden über Komplexverbindungen ohne Zuhilfenahme asymmetrischer Moleküle

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Generalization possibilities of autocatalytic absolute enantioselective synthesis

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Crystallization and solid-state reaction as a route to asymmetric synthesis from achiral starting materials

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Evolution in bioids: Hypercompetitivity as a source of bistability and a possible role of metal complexes as prenucleoprotic mediators of molecular asymmetry

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Asymmetric Synthesis by Using Natural Sunlight under Absolute Achiral Conditions

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Coupling Viedma Ripening with Racemic Crystal Transformations: Mechanism of Deracemization

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Absolute Asymmetric Synthesis: Viedma Ripening of [Co(bpy)3]2+ and Solvent‐Free Oxidation to [Co(bpy)3]3+

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Absolute Asymmetric Synthesis Involving Chiral Symmetry Breaking in Diels–Alder Reaction

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Effects of flows in auto-organization, self-assembly, and emergence of chirality

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Asymmetric Synthesis of an Amino Acid Derivative from Achiral Aroyl Acrylamide by Reversible Michael Addition and Preferential Crystallization

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Continuous Flow Chiral Amine Racemization Applied to Continuously Recirculating Dynamic Diastereomeric Crystallizations

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Chiral Symmetry Breaking of Monoacylated Anhydroerythritols and meso‐1,2‐Diols through Crystallization‐Induced Deracemization

Sanada, K., Washio, A., Ishikawa, H., Yoshida, Y., Mino, T., & Sakamoto, M. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202201268 · Cited by 21

Crystallization-induced diastereomer transformation of thiohydantoin derivatives

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Chiral Symmetry Breaking of Thiohydantoins by Attrition-Enhanced Deracemization

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Attrition-Enhanced Deracemization and Absolute Asymmetric Synthesis of Flavanones from Prochiral Precursors

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Histochemistry of myelin. XI. Loss of basic protein in early myelin breakdown and multiple sclerosis plaques

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Deracemization Controlled by Reaction-Induced Nucleation: Viedma Ripening as a Safety Catch for Total Spontaneous Resolution

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Designing single chirality via crystallization method: spontaneous chiral symmetry breaking and deracemization

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Solution‐Phase Racemization in the Presence of an Enantiopure Solid Phase

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Absolute Helical Arrangement of Sulfonamide in the Crystal

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Absolute Asymmetric Synthesis of an Aspartic Acid Derivative from Prochiral Maleic Acid and Pyridine under Achiral Conditions

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Chiral Selectivity of Secondary Nucleation in Amyloid Fibril Propagation

Törnquist, M., & Linse, S. S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202108648 · Cited by 19

Efficient Havinga–Kondepudi resolution of conglomerate amino acid derivatives by slow cooling and abrasive grinding

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Asymmetric Autocatalysis and Biomolecular Chirality

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Chiral Amplification through the Interplay of Racemizing Conditions and Asymmetric Crystal Growth

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Chiral symmetry‐breaking transition in growth front of crystal phase of 1,1′‐binaphthyl in its supercooled melt

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Astrobiology and Biological Chirality

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Origin of Homochirality of Amino Acids in the Biosphere

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Addition of bromine gas to crystalline dibenzobarrelene: An enantioselective carbocation rearrangement in the solid state

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On molecular asymmetry in living organisms

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Resolution of racemates with achiral reagents

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Search for chiral molecules and optical activity in extraterrestrial systems. Example of titan

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Asymmetric autocatalysis: crystallization-induced highly enantioselective synthesis of a conglomerating oxo-rhenium(V) complex

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Correlation of nitrogen chirality, R or S, with metal chelate chirality, Δ or Λ, in a series of reduced tripodal Schiff base complexes. A route to total spontaneous resolution

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9.16 Crystallization as a Tool in Industrial Applications of Asymmetric Synthesis

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THE CONCEPT OF RACEMATES AND THE SOAI-REACTION

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Stereochemistry and Organic Solid‐State Reactions

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Highly Stereoselective Strecker Synthesis Induced by a Slight Modification of Benzhydrylamine from Achiral to Chiral

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Dual Role of Hydrophobic Racemic Thioesters of α-Amino Acids in the Generation of Isotactic Peptides and Co-peptides in Water; Implications for the Origin of Homochirality

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Asymmetric Synthesis Involving Dynamic Enantioselective Crystallization

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Generation and amplification of optical activity by crystallization: the system nickel α-amino caprolactam/lysine.

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On Solute Recovery and Productivity in Chiral Resolution through Solid-State Deracemization by Temperature Cycling

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Asymmetric Synthesis of Indoline from Achiral Phthalimide Involving Crystallization‐Induced Deracemization

Nakamura, T., Ban, K., Yoshida, Y., Mino, T., Kasashima, Y., & Sakamoto, M. (2021) · Chemistry - A European Journal · doi:10.1002/chem.202103345 · Cited by 13

Chiral Symmetry Breaking of Racemic 3-Phenylsuccinimides via Crystallization-Induced Dynamic Deracemization

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Deracemization of Quinolonecarboxamides by Dynamic Crystalline Salt Formation and Asymmetric Photoreaction by Using the Frozen Chirality

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Asymmetric Synthesis Involving Reversible Photodimerization of a Prochiral Flavonoid Followed by Crystallization

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Asymmetric Crystallization of an Achiral Lariat-type Macrocyclic Compound

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4-Hydroxy-5-iod-2,3-dimethoxy-6-methylbenzoesäuremethylester: Der aromatische Teil von Calichemicin γ1αI; Synthese, Röntgenstrukturanalyse und Eigenschaften

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Lock‐And‐Key Processes at Crystalline Interfaces: Relevance to the Spontaneous Generation of Chirality

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Mechanistic Dissymmetry between Crystal Growth and Dissolution Drives Ratcheted Chiral Amplification

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Achiral‐to‐Chiral Transition in Benzil Solidification: Analogies with Racemic Conglomerates Systems Showing Deracemization

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Absolute asymmetric Strecker synthesis in a mixed aqueous medium: reliable access to enantioenriched α-aminonitrile

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Chiral Symmetry Breaking of Spiropyrans and Spirooxazines by Dynamic Enantioselective Crystallization

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Crystallisation-induced dynamic resolution of dipeptide-derived 5(4H)-oxazolones

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Asymmetric Transformation of N-Acyl- Dl -amino Acids

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Asymmetric Anisoin Synthesis Involving Benzoin Condensation Followed by Deracemization

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Absolute Asymmetric Synthesis Via Photochemical Reactions of Chiral Crystals

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Enantioselective Autocatalysis. V. The Spontaneous Resolution of Tri-o-Thymotide

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In Situ Observation of Chiral Symmetry Breaking in NaClO3 Chiral Crystallization Realized by Thermoplasmonic Micro-Stirring

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On a model chemical system related to absolutely asymmetric synthesis

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Attrition‐Enhanced Deracemization of Axially Chiral Nicotinamides

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Attrition-enhanced total resolution leads to homochiral families of amino acid derivatives

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Non‐stochastic behavior in sodium chlorate crystallization

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Speeding up Viedma Deracemization through Water‐catalyzed and Reactant Self‐catalyzed Racemization

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Spontaneous Emergence of Homochiral Suspensions from Racemic Solutions via Stochastic Nucleation

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Chirogenesis and Amplification of Molecular Chirality Using Optical Vortices

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Conditions for chiral asymmetry generation in the preparation of the chiral octahedral cobalt complex

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Chirality and the Origins of Life

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Molecular Chirality at Surfaces

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Pyramidal Stereogenic Nitrogen Centers (SNCs)

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Role of latent heat in chiral symmetry breaking transition in the crystallization of 1,1′‐binaphthyl

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Life's Single Chirality: Origin of Symmetry Breaking in Biomolecules

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A spontaneous asymmetric synthesis of optically active polymers by crystallization, lattice-controlled reaction, and autocatalytic induced recrystallization

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Rapid Discrimination of Crystal Handedness by X‐ray Natural Circular Dichroism (XNCD) Mapping

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Chemical amplification through competitive autocatalysis

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Studies on the Di-π-Methane Photorearrangement in the Solid State

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Enantioselective autocatalysis. II. Racemization studies on a 1,4-benzodiazepinooxazole derivative

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Behavior of All Chiral Standard Amino Acids for Chiral Symmetry Breaking of p-Anisoin

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Crystallisation Based Deracemisation and Chiral Resolution of Small Molecules

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Self-Replication of Chiral α-Amino Acids in Strecker-Type Synthesis via Asymmetric Induction and Amplification of Their Own Chiral Intermediate α-Aminonitriles

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2-Phenyl-3-hydroxyimidazolidin-4-one: the regioselective synthesis, structure and enantiomerically enriched crystallization

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XIV.—Abiogenic Information Coupling between Nucleic Acid and Protein, or, how Protein and DNA were married

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Chiral Selectivity of Secondary Nucleation in Amyloid Fibril Propagation

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Asymmetric Strecker Reaction Arising from the Molecular Orientation of an Achiral Imine at the Single‐Crystal Face: Enantioenriched l ‐ and d ‐Amino Acids

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Commentary: on the Origin of Optical Activity

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Exploring the enantioselective synthesis mechanism of ammonium cations in solution using deep learning potential

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Asymmetric Synthesis Using Crystal Chirality

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TOWARDS THE PLANNING AND EXECUTION OF AN “ABSOLUTE” ASYMMETRIC SYNTHESIS OF CHIRAL DIMERS AND POLYMERS WITH QUANTITATIVE ENANTIOMERIC YIELD

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Solid State Di-π-Methane Type Photorear-Rangements and a Case of Efficient Spontaneous Chiral Crystallization

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