The influence of metal lattice vacancies on the oxidation of high temperature materials
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Previous studies on duplex oxide scales have explained the constant ratio of inward- and outward-growing scales by the available space model.
“Previous studies on duplex oxide scales have explained the constant ratio of inward-and outward-growing scales by “the available space model” see, e. g.Gibbs et al. [48] or Martinelli et al. [49].”
The available space model holds that the growth of the inward-growing spinel is linked to the outward diffusion of iron, growing in the space created by vacancies in the alloy formed by outward iron diffusion.
“The model is based on that the growth of the inward-growing spinel is linked to the outward diffusion of iron by that it grows in the available space created by vacancies in the alloy formed as a result of outward diffusion of iron.”
Cited by
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Persdotter, A., Eklund, J., Liske, J., & Jonsson, T. (2020) · Corrosion Science · doi:10.1016/j.corsci.2020.108961 · Cited by 44 · see citing works
Effects of SO2 and SO3 on the Na2SO4 induced corrosion of nickel
Misra, A. K., & Whittle, D. P. (1984) · Oxidation of Metals · doi:10.1007/bf00659246 · Cited by 22 · see citing works
- Authors
- Gibbs, G. B., & Hales, R.
- Affiliations
- Central Electricity Generating Board (GB)
- Venue
- Corrosion Science
- Publisher
- Elsevier BV
- Published
- 1977-01
- Volume
- 17
- Issue
- 6
- Pages
- 487-507
- ISSN
- 0010-938X (ISSN-L)
- OpenAlex
- W2078417229
- Cited by
- 159
- References
- 0
- Citations by year
- 2026: 7 · 2025: 6 · 2024: 9 · 2023: 6 · 2022: 4 · 2021: 9 · 2020: 9 · 2019: 4 · 2018: 2 · 2017: 4 · 2016: 11 · 2015: 3 · 2014: 4 · 2013: 2 · 2012: 2
- FWCI
- 14.59
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Corrosion Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Aerospace Engineering › High-Temperature Coating Behaviors
- Physical Sciences › Engineering › Mechanical Engineering › High Temperature Alloys and Creep
- Physical Sciences › Engineering › Mechanical Engineering › Intermetallics and Advanced Alloy Properties
- Keywords
- lattice vacancies, vacancy injection, high-temperature oxidation, oxide scale growth, vacancy supersaturation, oxidation kinetics, carburizing, decarburization, breakaway oxidation
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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