The low temperature hot corrosion of iron and iron-aluminum alloys
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Fe-Al alloy has a peak corrosion rate at about 650°C because higher temperatures promote formation of protective Al2O3, which hinders penetration of molten salts to the base alloy.
“However, a peak in the corrosion rate is found at an intermediate temperature, i.e., about 650 o C, for the Fe-Al alloy since higher temperatures also promote the formation of the protective oxide Al2O3 which hinders the penetration of molten salts to the base alloy [23].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [23]
Pure iron beneath Na2SO4 in O2-(0.5-1.0%) (SO2+SO3) has a corrosion rate that grows with increasing temperature from 600°C to 700°C due to enhanced mass transfer and increased reaction rates.
“Shi et al. found the corrosion rate of pure iron beneath Na2SO4 in O2-(0.5-1.0%) (SO2 + SO3) grows with increasing temperature (600 o C - 700 o C) due to the enhanced mass transfer of all species and increased rate of all reactions.”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [23]
The corrosion rate of Fe-Al alloys (Fe-5Al and Fe-10Al) is much slower than that of pure iron beneath Na2SO4 in O2-(0.5-1.0%)(SO2+SO3) at 600-700 o C due to the formation of aluminum oxide.
“Shi et al. found the corrosion rate of Fe-Al alloys (Fe-5Al and Fe-10Al) is much slower than that of pure iron beneath Na2SO4 in O2-(0.5-1.0%) (SO2 + SO3) in temperature range from 600 o C to 700 o C due to the formation of aluminum oxide [23].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [23]
Cites
Effects of SO2 and SO3 on the Na2SO4 induced corrosion of nickel
Misra, A. K., & Whittle, D. P. (1984) · Oxidation of Metals · doi:10.1007/bf00659246 · Cited by 22 · see citing works
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A review on molten sulfate salts induced hot corrosion
Hu, S., Finklea, H., & Liu, X. (2021) · Journal of Materials Science & Technology · doi:10.1016/j.jmst.2021.03.013 · Cited by 183 · see citing works
Shi, L., Zhang, Y., & Shih, S. (1992) · Oxidation of Metals · doi:10.1007/bf00665661 · Cited by 13 · see citing works
Self-citation
- Authors
- Shi, L., Zhang, Y., & Shih, S.
- Affiliations
- Shanghai Institute of Microsystem and Information Technology (CN)
- Venue
- Corrosion Science
- Publisher
- Elsevier BV
- Published
- 1992-09
- Volume
- 33
- Issue
- 9
- Pages
- 1427-1438
- ISSN
- 0010-938X (ISSN-L)
- OpenAlex
- W2030348273
- Cited by
- 10
- References
- 1
- Citations by year
- 2026: 2 · 2022: 1 · 2021: 1 · 2020: 1 · 2016: 1 · 2015: 1
- FWCI
- 1.42
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Corrosion Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Aerospace Engineering › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Materials Chemistry › Corrosion Behavior and Inhibition
- Physical Sciences › Engineering › Mechanical Engineering › Intermetallics and Advanced Alloy Properties
- Keywords
- low temperature hot corrosion, iron, Fe-Al alloys, fluxing, oxide scale growth, eutectic melt, iron sulfate, sulfidation, oxygen partial pressure, aluminum content, high-temperature oxidation
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