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Cited by 431

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Molybdenum carbide catalysts

Open access
Lee, J.S., Oyama, S.T., Boudart, M.·1987·Journal of Catalysis

Abstract

Temperature-programmed reaction between MoO3 of low specific surface area Sg and a CH4H2 mixture produces unsupported powders of hexagonal Mo2C with Sg from 50 to 100 m2 g− and CO uptake number density of up to 5.0 × 1014 cm−2. Depending on the preparation conditions, this material can be synthesized with a surface free of contamination by noncarbidic carbon (Mo2C-I) or with a surface completely covered by polymeric carbon layers (C-Mo2C). For the latter case a method of treatment with dihydrogen was developed that removes the carbon contamination to create an active carbide surface (Mo2C-lI).

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Metadata

Authors
Lee, J. S., Oyama, S. T., & Boudart, M.
Venue
Journal of Catalysis
Publisher
Elsevier BV
Published
1987-07
Volume
106
Issue
1
Pages
125-133
ISSN
0021-9517 (ISSN-L)
OpenAlex
W1999891489
Cited by
431
References
0
FWCI
2.22
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Molybdenum carbide catalysts. https://app.cochat.ai/papers/10.1016/0021-9517(87)90218-1
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Lee, J. S., Oyama, S. T., & Boudart, M. (1987). Molybdenum carbide catalysts. Journal of Catalysis. https://doi.org/10.1016/0021-9517(87)90218-1

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.