Enthalpy relaxation and recovery in amorphous materials
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Embrittlement of PLLA can be caused by either enthalpy relaxation or crystallisation.
“This embrittlement can be caused by either enthalpy relaxation or crystallisation.”
From Tuning structural relaxations, mechanical properties, and degradation timescale of PLLA during hydrolytic degradation by blending with PLCL-PEG (2019) · cites this paper as [19]
Cites
An Algorithm for Least-Squares Estimation of Nonlinear Parameters
Marquardt, D. W. (1963) · Journal of the Society for Industrial and Applied Mathematics · doi:10.1137/0111030 · Cited by 30,728 · see citing works
Williams, M. L., Landel, R. F., & Ferry, J. D. (1955) · Journal of the American Chemical Society · doi:10.1021/ja01619a008 · Cited by 8,083 · see citing works
Studies in Newtonian Flow. II. The Dependence of the Viscosity of Liquids on Free-Space
Doolittle, A. K. (1951) · Journal of Applied Physics · doi:10.1063/1.1699894 · Cited by 1,831 · see citing works
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Enthalpy Relaxation and Embrittlement of Poly( <scp>l</scp> -lactide) during Physical Aging
Pan, P., Zhu, B., & Inoue, Y. (2007) · Macromolecules · doi:10.1021/ma071737c · Cited by 282 · see citing works
Allison, S. D. (2008) · Journal of Pharmaceutical Sciences · doi:10.1002/jps.21124 · Cited by 129 · see citing works
Pan, P., Liang, Z., Zhu, B., Dong, T., & Inoue, Y. (2008) · Macromolecules · doi:10.1021/ma801436f · Cited by 128 · see citing works
Molecular-weight dependence of enthalpy relaxation of PMMA
Andreozzi, L., Faetti, M., Giordano, M., & Zulli, F. (2005) · Macromolecules · doi:10.1021/ma0507037 · Cited by 74 · see citing works
Oosterbeek, R. N., Kwon, K.-A., Duffy, P., McMahon, S., Zhang, X. C., Best, S. M., & Cameron, R. E. (2019) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2019.109015 · Cited by 30 · see citing works
“Enthalpy relaxation (also known as physical aging), is a result of the thermodynamically unstable nature of the fast-cooled glassy polymer - the material tends to equilibrium through slow rearrangements, resulting in densification without long-range order, greater intermolecular interactions, and loss of ductility [17…”
Background
- Authors
- Hodge, I. M.
- Affiliations
- Carestream (United States) (US)
- Corresponding author
- Hodge, I.M.
- Venue
- Journal of Non-Crystalline Solids
- Publisher
- Elsevier BV
- Published
- 1994-04
- Volume
- 169
- Issue
- 3
- Pages
- 211-266
- ISSN
- 0022-3093 (ISSN-L)
- OpenAlex
- W1971318238
- Cited by
- 1,206
- References
- 3
- Citations by year
- 2026: 21 · 2025: 26 · 2024: 35 · 2023: 36 · 2022: 38 · 2021: 35 · 2020: 32 · 2019: 35 · 2018: 43 · 2017: 38 · 2016: 49 · 2015: 40 · 2014: 60 · 2013: 40 · 2012: 37
- FWCI
- 24.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Non-Crystalline Solids (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
- Physical Sciences › Engineering › Mechanical Engineering › Metallic Glasses and Amorphous Alloys
- Physical Sciences › Materials Science › Ceramics and Composites › Glass properties and applications
- Keywords
- enthalpy relaxation, enthalpy recovery, amorphous materials, non-exponential relaxation
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
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