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The crystal structure of rare-earth cobalt compounds of the type R3Co
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TbHo2Tm9Co4 is predicted to be monoclinic and non-centrosymmetric, space group Pm, with a = 6.14 Å, b = 9.23 Å, c = 6.89 Å, and β = 90.1°, representing an unlikely ordering of small lanthanides in a compound of composition Ln3Co; Ho3Co adopts a centrosymmetric orthorhombic Pnma structure with a = 6.92 Å, b = 9.29 Å, and c = 6.21 Å.
“TbHo2Tm9Co4 (mp-3170547) is an even more striking example among the intermetallics. This proposed alloy between three smaller rare earths and cobalt is predicted to be monoclinic and non-centrosymmetric, space group Pm, with a = 6.14 Å, b = 9.23 Å, c = 6.89 Å, and β = 90.1°.”
From Artificial Intelligence Driving Materials Discovery? Perspective on the Article: Scaling Deep Learning for Materials Discovery (2024) · cites this paper as [12]
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Research works printed but not linked: 6
- Nowvy, 1961, Trans. AIME, 221, 588
- Pelleg, 1965, J. Less-Common Metals, 9, 281, 10.1016/0022-5088(65)90021-4 · DOI
- Buschow, 1966, Z. Metallk., 57, 728
- Buschow, 1968, J. Less-Common Metals, 14, 323, 10.1016/0022-5088(68)90037-4 · DOI
- Cromer, 1961, Acta Cryst., 14, 1226, 10.1107/S0365110X61003594 · DOI
- Lemaire, 1967, Bull. Soc. Franc. Mineral. Crystallogr., 90, 311
Cited by
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Cheetham, A. K., & Seshadri, R. (2024) · Chemistry of Materials · doi:10.1021/acs.chemmater.4c00643 · Cited by 191
Metadata
- Authors
- Buschow, K. H. J., & Van Der Goot, A. S.
- Affiliations
- Philips (Netherlands) (NL)
- Venue
- Journal of the Less Common Metals
- Publisher
- Elsevier BV
- Published
- 1969-07
- Volume
- 18
- Issue
- 3
- Pages
- 309-311
- ISSN
- 0022-5088 (ISSN-L)
- OpenAlex
- W2031842825
- Cited by
- 80
- References
- 0
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 4 · 2023: 1 · 2022: 2 · 2020: 3 · 2019: 3 · 2018: 3 · 2017: 1 · 2015: 1 · 2014: 1 · 2013: 2 · 2012: 1
- FWCI
- 1.48
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the Less Common Metals (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Condensed Matter Physics › Rare-earth and actinide compounds
- Physical Sciences › Chemistry › Inorganic Chemistry › Inorganic Chemistry and Materials
- Physical Sciences › Chemistry › Inorganic Chemistry › Crystal structures of chemical compounds
- Keywords
- rare earth cobalt compounds, crystal structure, rare-earth cobalt oxides, intermetallic compounds
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